A Statistical Mechanical Analysis on the Bound State Solution of an Energy-Dependent Deformed Hulthn Potential Energy?

B.C.Ltfolu,A.N.Ikot,U.S.Okorie,,4and A.T.Ngiangia1Department of Physics,Faculty of Science,Akdeniz University,07058 Antalya,Turkey

2Department of Physics,Faculty of Science,University of Hradec Krlov,Rokitanskho 62,50003 Hradec Krlov,Czechia

3Department of Physics,Theoretical Physics Group,University of Port Harcourt,Choba,Port Harcourt,Nigeria

4Department of Physics,Akwa Ibom State University,Ikot Akpaden,P.M.B.1167,Uyo,Nigeria

(Received April 27,2019;revised manuscript received May 18,2019)

AbstractIn this article,we investigate the bound state solution of the Klein Gordon equation under mixed vector and scalar coupling of an energy-dependent deformed Hulthn potential in D dimensions.We obtain a transcendental equation after we impose the boundary conditions.We calculate energy spectra in four different limits and in arbitrary dimension via the Newton-Raphson method.Then,we use a statistical method,namely canonical partition function,and discuss the thermodynamic properties of the system in a comprehensive way.We find out that some of the thermodynamic properties overlap with each other,some of them do not.

Key words:Klein-Gordon equation,energy-dependent deformed Hulthn potential energy,bound state solution,thermodynamic properties

1 Introduction

One of the major investigation areas in either relativistic or non-relativistic quantum mechanics is to obtain a solution of potential energies.[1?4]This intense interest is based on the fact that the exact solution of the wave function has all the necessary information to define the physical system.Unfortunately,only a few numbers of potential energies have exact solutions.Unfortunately,only a few numbers of potential energies have exact solutions,for example,infinite well,finite well or barrier,Coulomb potential,and the harmonic oscillator.Beside these analytic solutions,semi exact solutions in case of l=0,or approximate solutions in case of l≠0 are investigated comprehensively in many other potential energies such as Morse,[5]Eckart,[6]Rosen-Morse(RM),[7]Manning-Rosen(MR),[8]Pschl-Teller(PT),[9]Yukawa,[10]Hylleraas,[11]Hulthn,[12]Woods-Saxon(WS),[13]etc.

The Klein-Gordon(KG)equation is one of the fundamental relativistic wave equation that describes the motion of spin zero particles.[14]Remarkable efforts have been executed to examine the solutions of the KG equation with a various number of potential energies.Yi et al.employed RM type vector and scalar potential energies to obtain the s-wave bound state energy spectra.[15]Villalba et al.examined the bound state solution of a spatially one-dimensional cusp potential energy in the KG equation.[16]Olgar et al.employed a supersymmetric technique to obtain a bound state solution of the s-wave KG equation with equal scalar and vector Eckart type potential energy.[17]Only two years later,they applied the asymptotic interaction method(AIM),which is originally introduced by Ciftci et al.,[18]to calculate an energy spectrum of the s-wave KG equation with the mixed scalar and vector generalized Hulthn potential in one dimension.[19]Then,he used AIM to investigate bound state solution of three different potential energies,namely linear,Morse and Kratzer,in the KG equation.[20]In 2010,Xu et al.studied the bound state solution of the KG equation with mixed vector and scalar PT potential energy with a non zero angular momentum parameter.[21]Ikot et al.obtained an exact solution of the Hylleraas potential energy in the KG equation.[22]Jia et al.examined the bound state solution of the KG equation with an improved version of the MR potential energy.[23]Hou et al.studied the bound state solution of the s-wave KG equation with vector and scalar WS potential energy.[24]Rojas et al.used the vector WS barrier in the KG equation and presented the continuum state solution.[25]Later,Hassanabadi extended that study with an addition of scalar WS potential energy term.[26]Arda et al.employed Nikiforov-Uvarov(NU)and studied the modified WS potential energy with position dependent mass in the KG equation in three dimensions.[27]Badalov et al.used NU and Pekeris approximation to study any l state of the KG equation.[28]Bayrak et al.investigated the generalized WS potential energy in the KG equation for zero[29]and non-zero[30]values of the angular momentum parameter.One of the authors of this manuscript,Ltfolu,with his collaborators examined the mixed vector and scalar generalized symmetric WS potential energies for the scattering case in the KG equation first under the equal magnitudes and signs(EMES),and then,in the equal magnitudes and opposite signs(EMOS).[31]Later,he investigated the same problem in the bound state case.[32]Beside these studies,multi-parameter exponential type potential energies[33?35]and non central potentials[36?37]are examined in the KG equation.

Recently,the investigation of different physical systems in one or three dimensions have been extended to higher dimensions to describe different phenomena not only in diverse fields of physics but in quantum chemistry,too.[38]Chen et al.examined hydrogen type atoms by employing the Couloumb potential energy in KG equation in D dimensions.[39]Saad et al.applied AIM to study KG equation with unequal vector and scalar Kratzer potential energy in D dimensions.[40]In 2011,Hassanabadi et al.obtained an approximate solution by employing an equal scalar and vector generalized Kratzer potential to the D-dimensional KG equation for any angular momentum parameter.[41]One year later,Hassanabadi et al.examined the Eckart potential in addition to modified Hylleraas potential energy in higher dimensional relativistic equations by supersymmetric quantum mechanic methods.[42]Ibrahim et al.studied higher dimensional KG and Dirac equations with mixed equal scalar and vector RM potential energies by NU method.[43]Ortakaya used pseudoharmonic oscillator potential energy in D-dimensional KG equation to obtain the bound state energy spectrum of CH,H2and HCl molecules.[44]Antia et al.defined a combined potential energy function by addition of Mobius square potential to Yukawa potential energy.Then,they employed the NU method to solve the combined potential energy in high dimensional KG equation.[45]Chen et al.obtained the relativistic bound state energy equation by employing the improved MR potential energy in D spatial dimensions.[46]Ikot et al.analyzed the improved MR potential energy for arbitrary angular momentum parameter in an approximate method in D dimensions.[47]Tan et al.and Jia et al.solved the D-dimensional KG equation with the improved and modified RM potential energy by employing supersymmetric WKB approximation.[48?49]Xie et al.examined Morse potential energy in KG equation to derive the bound state energy equation in D spatial dimensions.[50]Ikot et al.employed NU method to analyze an exponential type molecule potential in the KG equation in D dimensions.[51]

In last decade,the prediction of the properties of a physical system by investigating their thermodynamic functions become popular.In this purpose,the scientist calculates the energy spectrum of the system in a relativistic or non-relativistic equation by proposing potential energy and then obtains the partition function.Ikhdair et al.solved the Schrdinger equation with the PT potential energy via AIM and discussed the thermodynamic functions.[52]In 2014,Oyewumi et al.used the shifted Deng-Fan potential energy in the non-relativistic equation to analyze the statistical properties.[53]One year later,Onate et al.defined the combination of hyperbolical and generalized PT potential energies and solved Dirac equation.They discussed the thermodynamic properties in non relativistic limit in addition to the spin symmetry(SS)and pseudospin symmetry(PSS)limits.[54]In 2016,Arda et al. used the linear potential to investigate the thermodynamic quantities such as the Helmholtz free energy,and the mean energy with the specific heat function in both KG and Dirac equations.[55]Onyeaju et al. studied the Dirac equation with the deformed Hylleraas in addition to WS potential energy and calculated the thermodynamic functions of some diatomic molecules.[56]Then,Ikot et al.discussed the thermodynamic functions of diatomic molecules by using a general molecular potential.[57]In another paper,Valencia-Ortega and Arias-Hernandez investigated the thermodynamic properties of diatomic molecules by adopting SO(2,1)anharmonic Eckart potential energy.[58]Furthermore,Okorie with co-authors investigated thermodynamic functions by using modified Mobius square,[59]modified Yukawa,[60]quadratic exponential-type,[61]shifted Tietz-Wei[62?63]potential energies. In 2019,one of the authors of the present paper,Ikot,with his collaborators studied the thermodynamic properties of a q-deformed quantum oscillator in the scale of minimal length.[64]The other author of the present paper,Ltfolu,also contributed to the field by the studies via the investigation of the generalized symmetric WS potential energy in non relativistic[65]and relativistic equations.[66]With the non relativistic results,they obtained the thermodynamic properties of a nucleon in relatively small[67]and big radius nuclei.[68]Then,he compared the thermodynamic functions with excluding and including the surface effects in non-relativistic,[69]and relativistic regimes.[70]In a very recent article,they presented the variance of the thermodynamic functions in the existence of attractive or repulsive surface interaction terms.[71]Besides these works,thermodynamic properties of molecules and dimers are examined in several articles by taking the vibrational and rotational partition functions into account.[72?88]

Our motivation is to determine the bound state solution of the energy-dependent deformed Hulthn potential in D-dimensional KG equation and discuss the corresponding thermodynamic functions.Note that the energy-dependent potential energies have been investigated in both relativistic and non-relativistic wave equations since 1940.[89?95]In recent times,Gupta et al.studied the Schrdinger equation with energy dependent harmonic oscillator potential energy function to describe quark systems.[96]Ikot et al.examined energy dependent Yukawa potential energy with a Coloumb-like tensor interaction in the Dirac equation at the SS and PSS limits.[97]Boumali et al.examined energy dependent harmonic oscillator in Schrdinger[98]and KG equation[99]to predict the Shannon entropy and Fisher information.

The paper is organized as follows.In Sec.2 we define the KG equation in an arbitrary dimension with the vector and the scalar potential energy coupling.Then,we describe q-deformed energy dependent Hultn potential energy and obtain the radial wave function solution by employing a Greene-Aldrich approach to the centrifugal term.Furthermore,we derive the quantization condition.Before we end the section,we briefly give the normalization method in an energy dependent potential energy case.In Sec.3 we state the thermodynamic functions such as Helmholtz free energy,entropy,internal energy,and specific heat.Then,in Sec.4 we use the Newton-Raphson method to calculate energy spectra for various dimensions in the EMES,EMOS,pure vector and scalar limits.Moreover,we obtain the thermodynamic functions from the partition function.We demonstrate those functions within a comparison.In Sec.5 we conclude the paper.

2 Solutions of the Klein-Gordon Equation in

DDimensions

We start by expressing the KG equation in D spatial dimensions with

In this manuscript,we investigate the solution of the spherical symmetric potential energies that are timeindependent.Therefore,we can separate the wave function into time and spatial components.Then,we decompose the spatial part of the wave function into radial and angular parts by employing the spherical symmetric nature of the potential energies.Finally,we obtain the radial equation as follows.

Here γ ≡ [(D+2l?1)(D+2l?3)]/4,and l denotes the angular momentum quantum number.Furthermore,represents the Planck constant,and g is the coupling constant that is nearly equal to one in the strong regime.Note that χ(r)rR(r).In the rest of the article,we will use the natural units where=c=1.

2.1 Bound State Solutions

We examine q-deformed energy dependent vector and scalar Hulthn potential energy wells

where V0,S0,a,and δ are the vector potential depth,scalar potential depth,energy slope parameter,and the screening parameters,respectively.

In order to deal with the centrifugal term we adopt the Greene-Aldrich approximation scheme[100]

Here,δr<1 and q? 1.Note that for the validity,the deformation parameter value should not be higher than 1.Then,we substitute Eq.(3),Eq.(4),and Eq.(5)into Eq.(2)and we get

We introduce a new coordinate transformation of the form z ≡ (1?q e?δr)?1,and adopt the following abbreviations

We get

Then,we propose the following ansatz

where

We find that Eq.(11)turns into the following form

The solution can be expressed in terms of the hypergeometric functions2F1

where

2.2 Quantization

In this subsection,we take into account the boundary condition that dictates the radial wave function should go to zero at infinity.In that limit,the transformed coordinate z goes to 1.Therefore,we need to determine the behaviour of the hypergeometric function initially.We employ the following well-known property of the hypergeometric function[101]

Then,we find

After this identical transformation of the hypergeometric functions,the result values are equal to 1.Consequently,we get

where

We assume that ν = α.We are obliged to take N2=0 and Γ2=0 to avoid the singularity.We use the definition of the reciprocal of gamma function for negative integer as given in Ref.[101],

to eradicate Γ2. Although either μ+ ν+1/2? θ or μ+ν+1/2+θ can be chosen to be equal to?n,the symmetric structure of the wave functions under exchange of both parameters leads to obtain the same solution.We use the condition

and we obtain

where

We find the unnormalized radial wave function as follows

2.3 The Normalization of the Radial Wave Function with Energy Dependent Potential Energies

Benchikha et al.examined the energy dependent potential energy in non-relativistic[94]and relativistic[95]equations.They modified the well-known probability density definition for the KG equation with the following expression

Consequently,in the problem one can calculate the normalization constant as follows

Here,we skip calculating the normalization constant since it does not exist in our main motivation.

3 Thermodynamic Functions

One way to examine the thermodynamic properties of a physical system is to use the partition function.In the canonical ensemble,for a system that is in an equilibrium state,the partition function is defined with

Here,Enrepresents the available microstate energy values.βTis the reciprocal temperature function and it is inversely proportional to the multiplication of the Boltzmann constant with the absolute temperature.Thermodynamic functions such as Helmholtz free energy,F(βT),entropy,S(βT),internal energy,U(βT),and specific heat,Cv(βT),functions are obtained from the partition function as follows

4 Results and Discussions

In this section,we construct the thermodynamic functions just after we calculate the energy spectra in different limits and dimensions.To calculate the energy spectra we solve the quantization condition numerically by the use of the Newton-Raphson method in the EMES limit,V0=S0,in the EMOS limit,V0=?S0,in the pure vector limit,S0=0,and in the pure scalar limit,V0=0.Note that,since we study with the natural units,all units of the parameters of the system can be expressed in terms of energy or reciprocal energy.There are some parameters that are always kept as a constant in all limits,for instance,the mass and the deformation parameter.Both of them are equal to one.There are some other parameters,which we assign different values,i.e.,a parameter,which is the measure of the energy dependence of the potential energy,is assumed to be equal to 1(1/E),0,and?1(1/E).Note that,we calculate the spectra only in 3,4,and 5 dimensions.

In the second part of this section,namely in Subsec.4.5,we employ the obtained energy spectra to discuss the thermodynamic functions of the system.

4.1 EMES Limit

We assume the energy depth parameters have equal values as given,V0=S0=2(E).Moreover,the slope parameter is equal to 0.01(E).We tabulate the energy spectra in three dimensions in Table 1,in four dimensions in Table 2,and in five dimensions in Table 3,respectively.

Table 1 Energy spectrum for the EMES limit in three dimensions.

Table 2 Energy spectrum for the EMES limit in four dimensions.

Table 3 Energy spectrum for the EMES limit in five dimensions.

4.2 EMOS Limit

In this limit,the energy depth parameters have negatively equal values.Here,we assume V0=2(E)and S0=?2(E).Alike EMES limit,we choose the slope parameter to be equal to 0.01(E).Then,we present the energy spectra in three dimensions in Table 4,in four dimensions in Table 5,and in five dimensions in Table 6,respectively.

Table 4 Energy spectrum for the EMOS limit in three dimensions.

We see that when the energy dependence is fixed with ε=1?E,(a= ?1(1/E)),most of the eigenvalues in the energy spectrum cannot be calculated.Therefore,we decide to calculate the spectrum for higher values oflparameter.Surprisingly,unlike ε=1+E case,the values oflparameter are not limited.In three,four and five dimensions we repeat the calculations and present them in Table 7,in Table 8,and in Table 9,respectively.We conclude that as the values of parameter l increase,energy eigenvalues converge.

Table 6 Energy spectrum for the EMOS limit in five dimensions.

Table 7 Energy spectrum for the EMOS limit in three dimensions for the higher values of l.

Table 8 Energy spectrum for the EMOS limit in four dimensions for the higher values of l.

4.3 Pure Vector Limit

Table 10 Ground state energy spectra in the pure vector limit.

In this limit,the scalar potential energy term is taken to be zero.Alike the previous limits,we assume that the V0=2(E).Unlike,we examine two different values of the slope parameter and tabulate it in Table 10.We find that when the energy dependence is lost,only one value of energy appears in the spectrum.

4.4 Pure Scalar Limit

In this limit,the scalar potential energy term is equal to 2(E),while the vector potential energy term is zero.Alike the pure vector limit,we examine two different values of the slope parameter.We present the results in Table 11.We find that there is only one energy eigenvalue in pure scalar spectra unlike the vector limit.Moreover,when the potential energy does not depend on energy,ground state energy eigenvalues do not occur.

Table 11 Ground state energy spectra in the pure scalar limit.

4.5 Thermodynamic Properties

Fig.1(Color online)Comparison of the partition functions versus the temperature in the EMES limit.

In this subsection,we use the EMES limit case results to examine the thermodynamic properties of the system.Therefore,we only employ Table 1,Table 2,and Table 3 to construct the partition function.

First,we use of the energy eigenvalues for a=1(1/E),a=0(1/E),and a=?1(1/E)in three dimensions from Table 1.We calculate the partition functions from Eq.(35)and plot them in the first column of Fig.1.Then,we use the energy spectra in three,four and five dimensions for the a=1(1/E)case from Table 1,Table 2,and Table 3.We present the plot of the partition functions in the second column of Fig.1.We see that the partition functions in three and four dimensions overlap.

We obtain the Helmholtz free energy functions by employing Eq.(36).We demonstrate the three-dimensional results in the first column of Fig.2.We see that Helmholtz free energy function for energy-dependent function cases has a very close appearance.We put forth the higher dimensional cases results in the second column of Fig.2.We find out that the overlapping of the thermodynamic functions is still valid.

Fig.2 (Color online)Comparison of the Helmholtz free energy functions versus the temperature in the EMES limit.

Fig.3 (Color online)Comparison of the entropy functions versus the temperature in the EMES limit.

We derive the entropy function from the Helmholtz free energy via Eq.(37).We show entropy functions versus lower temperature and relatively higher temperature in Fig.3.The entropy function in three dimensions behaves like the entropy function of five dimensions at low temperatures,while it behaves like the entropy function obtained in four dimensions at relatively high temperatures.Another finding is,in three dimensions at a lower temperature the entropy functions for a=0 and a=?1(1/E)case act similar to each other while at a relatively high temperature not.

Then,we use Eq.(38)to compute the internal energy functions.We present internal energy functions in Fig.4 versus temperature.We conclude that mean energy values are compatible with the results.

Fig.4 (Color online)Comparison of the internal energy functions versus the temperature in the EMES limit.

Fig.5 (Color online)Comparison of the specific heat functions versus the temperature in the EMES limit.

Finally,we achieve the specific heat function with the help of Eq.(39).We present them in Fig.5 versus temperature.We conclude that at a relatively higher temperature in all dimensions the characteristic of the functions for a=1(1/E)case,remains the same.On the other hand,in three dimensions,the specific heat function of a=?1(1/E)case,differs from others.

5 Conclusion

In this article,we investigated the bound state solutions of a mixed vector and scalar energy-dependent deformed Hulthn potential in the KG equation in arbitrary dimension.We obtained a transcendental equation,which yields to the quantization of the energy eigenvalues by the use of the necessary boundary conditions.Then,we employed the Newton-Raphson method to calculate energy spectra in the limits of the EMES,EMOS,pure vector and pure scalar.Finally,we used the canonical partition function definition and derived other thermodynamic functions,such as Helmholtz free energy,entropy,internal energy,and specific heat.Then,we discussed thermodynamic properties with energy dependency and dimensional effects.

Acknowledgment

The authors thank the kind reviewers of the article for the positive comments and suggestions that lead to an improvement in the quality of the article.