Effects of Mn substitution on thermoelectric properties of CuIn1?x Mn x Te2?

Pengfei Luo(羅鵬飛),Li You(游理),Jiong Yang(楊炯),Juanjuan Xing(邢娟娟), Jiye Zhang(張繼業(yè)),Chenyang Wang(王晨陽(yáng)),Xinluo Zhao(趙新洛), Jun Luo(駱軍),?and Wenqing Zhang(張文清),,?

1 Department of Physics,Institute of Low-Dimensional Carbons and Device Physics, Shanghai University,Shanghai 200444,China

2 Materials Genome Institute,Shanghai University,Shanghai 200444,China

3 School of Materials Science and Engineering,Shanghai University,Shanghai 200444,China

Effects of Mn substitution on thermoelectric properties of CuIn1?xMnxTe2?

Pengfei Luo(羅鵬飛)1,2,Li You(游理)3,Jiong Yang(楊炯)2,Juanjuan Xing(邢娟娟)3, Jiye Zhang(張繼業(yè))3,Chenyang Wang(王晨陽(yáng))3,Xinluo Zhao(趙新洛)1, Jun Luo(駱軍)3,?and Wenqing Zhang(張文清)2,3,?

1 Department of Physics,Institute of Low-Dimensional Carbons and Device Physics, Shanghai University,Shanghai 200444,China

2 Materials Genome Institute,Shanghai University,Shanghai 200444,China

3 School of Materials Science and Engineering,Shanghai University,Shanghai 200444,China

CuIn1?xMnxTe2samples have been synthesized by a melt-annealing method.The x-ray powder diffraction(XRD) analysis shows that the CuIn1?xMnxTe2samples crystallize in the chalcopyrite phase.Mn doping can effectively optimize the electrical properties and accordingly improve the power factor.The room temperature electrical conductivity of doped CuInTe2increases by several orders of magnitude due to substituting In with Mn.In addition,a large reduction in thermal conductivity is achieved through the enhanced phonon scattering via Mn-related point defects and precipitates.Therefore, an enhanced average Z T value up to 0.34 is achieved for sample CuIn0.925Mn0.075Te2,which is 41%higher than that of the pristine CuInTe2.

thermoelectrics,chalcopyrite,CuInTe2,Mn doping

1.Introduction

Thermoelectric conversion technology,which could convert heat into electricity for power generation or vice versa convert electrical energy into heat for refrigeration,provides a possible solution for the energy shortage and environmental concerns.[1–3]However,the low conversion efficiency limits the large-scale application of thermoelectric technology,which is determined by the dimensionless thermoelectric figure-of-merit(Z T).Z T is defined as Z T=S2σT/κ,where S is the Seebeck coefficient,σ the electric conductivity,T the absolute temperature,and κ the thermal conductivity,respectively.

Recently,much effort has been focused on ternary I–III–V I2-type(I=Cu,Ag;III=Al,Ga,In;and V I= S,Se,Te)chalcopyrite compounds owing to their nontoxicity,low lattice thermal conductivity,and good electrical transport properties.[4–13]So far,many compounds with high Z T values have been reported,for example,CuGaTe2with a Z T value of 1.4,[14]Ag0.95GaTe2with a Z T value of 0.77,[15]Cu1?xMnxInTe2with a Z T value of 0.84[16]and CuInTe1.99Sb0.01+1 wt%ZnO system with a Z T value of 1.61.[4]Among these ternary chalcopyrite compounds,p-type CuInTe2are characterized by relatively high Seebeck coefficient and low high-temperature thermal conductivity,owing to its degenerate valence bands[4]and highly distorted crystal structure,[7]respectively,which makes it a promising high temperature thermoelectric material.Nevertheless,the further application of un-doped CuInTe2is still retarded by its poor electrical conductivity and high room-temperature thermal conductivity.Therefore,it is desirable to develop a strategy to improve the electrical conductivity of CuInTe2and simultaneously suppress its lattice thermal conductivity.[4,12]In this work,we find that Mn is a desired doping element to improve both the electrical and thermal transport properties of CuInTe2.Through replacing part of In with Mn,the electrical conductivity of the CuIn1?xMnxTe2sample increases dramatically since Mn element acts as the acceptor to provide additional charge carriers(hole).Meanwhile,the elemental substitution leads to obviously reduced lattice thermal conductivity due to the enhanced phonon scattering.Therefore,enhanced thermoelectric performance is obtained for CuIn1?xMnxTe2, resulting from synergistic effect of optimized electrical conductivity and reduced lattice thermal conductivity.

2.Experimental section

Polycrystalline samples of CuIn1?xMnxTe2(x=0,0.025, 0.05,0.075,0.1)were synthesized by a melt-annealing method.The starting materials Cu(99.99%,shot),In (99.999%,shot),Mn(99.999%,piece),Te(99.999%,shot) were weighed according to the stoichiometric ratio and sealedin evacuated quartz tubes,which were heated to 1173 K at a rate of 1 K/min and held at this temperature for 24 h.Then,the samples were slowly cooled to 923 K,annealed at 923 K for 72 h,and cooled to room temperature in the furnace.Finally, to obtain densified bulk samples,the as-prepared ingots were crushed into fine powders and then vacuum sintered in a hot pressing furnace at 823 K for 15 min under an axial pressure of 65 MPa.

Phase identification and structure analysis were carried out by x-ray powder diffraction(XRD)using a Rigaku D/max 2200 diffractometer equipped with Cu-Kα radiation(45 kV, 250 mA).The microstructures of the polished hot-pressed samples were investigated by scanning electron microscope (Zeiss Supra 55,Germany).An electron energy x-ray dispersive spectroscopy(EDXS,Oxford)was equipped for elemental mapping and point analysis.The density D of hot pressed samples was determined by the Archimedes’method and found to be over 97%of the theoretical density.The heat capacity CPwas obtained using Dulong–Petit model, CP=3nR/M,where n is the number of atoms per formula unit, R is the gas constant,and M is the molar mass.Thermal diffusivity(λ)was measured by the laser flash method using a Netzsch LFA457 instrument.The thermal conductivity was calculated from the equation κ=CPDλ.The resistivity ρ and Seebeck coefficient S were measured via four probe method utilizing ZEM-3 instrument(ULVAC,Japan)under low-pressure helium atmosphere.The room-temperature carrier concentrations of the samples were obtained from Hall coefficient measurements,which were conducted on a mini cryogen free measurement system(Cryogenic Limited,UK).

3.Results and discussion

Figure 1(a)shows the XRD patterns of CuIn1?xMnxTe2samples(x=0,0.025,0.05,0.075,0.1).For all these samples, their diffraction peaks can be solely indexed to the chalcopyrite phase(PDF#81-1937)and no impurities are observed. All the XRD patterns were analyzed by Rietveld refinement. The obtained lattice parameters of the a-axis are shown in Fig.1(b).It can be seen that the lattice parameter,a,linearly decreases with the Mn contents when x＜0.075,indicating the replacement of In3+(0.80?A)by smaller Mn2+(0.67?A). Higher Mn content did not lead to further decrease in a,ascribed to the solid solubility limit of Mn.

Fig.1.(color online)(a)The XRD patterns and(b)lattice parameters of the a-axis for CuIn1?x Mn x Te2(x=0,0.025,0.05,0.075,0.1)samples. The gray line in panel(b)is guide for eyes.

Fig.2.(color online)BSE images of the samples with(a)5%Mn and(b)7.5%Mn.The magnified image of 7.5%Mn sample and Mn elemental mapping of boxed area are shown in panels(c)and(d),respectively.

Figure 2 presents the backscattered electron(BSE)microscopy of the polished surface for typical samples with x= 0.05 and 0.075.As shown in Fig.2(a),the BSE image of the sample with 5%Mn reveals a typical homogeneous solid solution microstructure and no obvious second phase precipitates can be found.However,for the sample with 7.5%Mn(see Figs.2(b)and 2(c)),particle-like precipitates with sizes from severalto 200 nm can be clearly observed,which are randomly distributed in the CuInTe2matrices.Thus,we can conclude that the solubility of Mn is between 5%and 7.5%.The precipitates cannot be identified in the XRD patterns,possibly due to their low content and tiny size.The elemental mapping (Fig.2(d))reveals that the precipitates have Mn-rich compositions.

Fig.3.(color online)The temperature dependence of(a)electrical conductivity,(b)Seebeck coefficient,(c)power factor for CuIn1?x Mn x Te2 (x=0,0.025,0.05,0.075,0.1)samples.

The electrical transport properties for CuIn1?xMnxTe2samples(x=0,0.025,0.05,0.075,0.1)are compared in Fig.3. As shown in Fig.3(a),the electrical conductivity of the pristine CuInTe2sample increases with the rising temperature, exhibiting the typical behavior of intrinsic semiconductors. However,when Mn is doped,the room-temperature electrical conductivities of CuIn1?xMnxTe2are dramatically increased, and the temperature dependence of conductivities becomes the behavior of degenerate semiconductors,indicating that the carrier concentrations of the samples were substantially enlarged by Mn doping.The measured room-temperature hole concentrations(nh)and Hall mobilities of carriers(μH)for the CuIn1?xMnxTe2samples are listed in Table 1.It can be seen that the hole concentrations of the samples increase with the increase of Mn contents.It has been reported that the hole concentration of the Mn-free CuInTe2is about 5.75× 1018cm?3.[12]Consequently,the room-temperature electrical conductivity of the sample with x=0.1 is～46600 S/m,which is more than 40 times larger than that of the sample free of Mn (about1100 S/m).Furthermore,the increasing of the hole concentrations suppresses the intrinsic excitation of charge carriers.Thus,the occurrence of bipolar conduction is pushed to higher temperatures with increasing Mn contents.

Table 1.Room temperature hole concentrations(n h)and Hall mobilities of carriers(μH)for the CuIn1?x Mn x Te2(x=0.025,0.05,0.075, 0.1)samples.

Figure 3(b)shows the temperature-dependent Seebeck coefficient of CuIn1?xMnxTe2samples.Positive Seebeck coefficients reveal the p-type hole dominant conduction in all the samples.The variation trend of the Seebeck coefficient with temperatures is opposite to that of the electrical conductivity.The Seebeck coefficient of the pristine CuInTe2sample decreases with the temperature increasing,further proving that the undoped sample is a non-degenerate semiconductor,whereas the Seebeck coefficient for the samples doped with Mn increases with the temperature increasing,exhibiting a behavior of degenerate semiconductors.As the Mn content increases,the Seebeck coefficients at 340 K reduce from 424μV/K for the pristine sample to 130μV/K for the sample with x=7.5%.The Seebeck coefficients for the samples with x=0.075 and 0.1 were found to be almost identical at lower temperature range.One possible reason is that the solid solubility of Mn in CuInTe2is below 0.075.The increased electrical conductivity and moderately decreased Seebeck coefficients lead to enhanced power factors(PF)in the temperature ranging from room temperature to 720 K(Fig.3(c)).A maximum PF of 11.2μV·cm?1·K?2at 625 K is achieved for the sample with x=0.05,which is much larger than that for CuInTe2at 625 K.

Fig.4.(color online)The temperature dependence of(a)total thermal conductivities,(b)Lorentz numbers,(c)electronic thermal conductivities, and(d)lattice thermal conductivities for CuIn1?x Mn x Te2(x=0,0.025,0.05,0.075,0.1)samples.The dashed line in panel(d)is the curve for T?1 relationship.

Figure 4 depicts the temperature-dependent thermal transport properties of the samples.As shown in Fig.4(a),the introduction of Mn can substantially reduce the total thermal conductivities(κtot).Lattice thermal conductivity(κL)can be obtained from κtotby subtracting the electronic part(κe)according to the relationship of κtot=κL+κe.Electronic thermal conductivity κecan be calculated from the electrical conductivity by the celebrated Wiedemann–Franz law κe=LσT, where L is the Lorenz number.[17]The Lorenz number in degenerate semiconductors can be calculated by Seebeck coefficient within a single parabolic model,using the following equations:[18]

where kB,e,and η are the Boltzmann constant,electron charge,and reduced Fermi energy(Fermi energy divided by kBT),respectively,and Fn(η)is the n-th Fermi–Dirac integral.The Lorenz number(L)can be calculated using Eq.(2) with the values of η,which are fitted from the experimental data of Seebeck coefficients by Eq.(1).The calculated Lorenz numbers and related electronic thermal conductivities of all the samples are illustrated in Figs.4(b)and 4(c),respectively.It can be derived from Fig.4(c)that κeincreases with the increase of Mn contents(i.e.,electrical conductivities).Consequently,the large reduction in κtotmainly comes from the decreased κL(see Fig.4(d)),which can be ascribed to the addition of Mn.It can be seen in Fig.4(d)that κLof all the samples approximately follow a T?1relationship(the dashed line in Fig.4(d)),indicating that the dominant phonon scattering mechanism should be the three-phonon Umklapp scattering process(U-process).[19]The incorporation of Mn can introduce a large number of point defects that can scatter short-wavelength phonons and thus mainly decrease the hightemperature lattice thermal conductivities.Additionally,nanosized precipitates occurring in samples with higher Mn concentrations can provide extra phonon scattering center for mid wavelength phonons,which can effectively reduce the lattice thermal conductivities near room temperatures.The further reduced κLat lower temperatures for samples with x=0.075 and 0.1 can be attributed to their additional nanosized precipitates.

The temperature-dependent dimensionless thermoelectric figure-of-merit Z T of CuIn1?xMnxTe2compounds is calculated based on the above transport data and is plotted in Fig.5. The Z T values increase when approaching high temperature, and reach a maximum value of～0.8 at 813 K for the sample with x=0.075,which is slightly higher than that of the pristine CuInTe2sample.Nevertheless,the average Z T is also an important factor for actual thermoelectric applications.[20]The calculated average Z T for all the samples is shown in the inset of Fig.5.It can be seen that the average Z T of all the samples with Mn incorporation is much higher than that of the pristine one and is up to 0.34 for the samples with x=0.075 and 0.1, owing to their moderate power factors and low lattice thermal conductivities in lower temperature range.

Fig.5.(color online)Influence of Mn contents on figure of merit Z T for CuIn1?x Mn x Te2 samples.The inset is the average Z T calculated from the integration using the formula

4.Conclusion

In summary,polycrystalline chalcopyrite CuIn1?xMnxTe2compounds(x=0,0.025,0.5,0.075,0.1)has been successfully synthesized.The solubility of Mn in CuInTe2is determined to be below 7.5%.By substituting In,Mn acts as an effective acceptor dopant and can dramatically improve the electrical transport properties of the pristine CuInTe2system.In addition,κLof the CuInTe2system can be substantially decreased by the point defects and nanosized precipitates introduced by the incorporation of Mn,and thus resulting in a considerably reduction in κtot.As a result,an enhanced average Z T value up to 0.34 is achieved for sample CuIn0.925Mn0.075Te2,which is 41%higher than that of the undoped CuInTe2,making it a promising candidate for thermoelectric applications.Furthermore,it is reported that anions (P3?,Sb3?)doping on the Te sites can effectively increase the Seebeck coefficient and consequently enhance the PF of the system.[4]Thus,introducing anion dopants plus some additional microstructure engineering in our Mn-doped CuInTe2system may bring its Z T value to that of the state-of-the-art thermoelectric materials.

[1]Zhao L D,Lo S H,Zhang Y,Sun H,Tan G,Uher C,Wolverton C, Dravid V P and Kanatzidis M G 2014 Nature 508 373

[2]Liu H,Shi X,Xu F,Zhang L,Zhang W,Chen L,Li Q,Uher C,Day T and Snyder G J 2012 Nat.Mater.11 422

[3]Pei Y,Shi X,LaLonde A,Wang H,Chen L and Snyder G J 2011 Nature 473 66

[4]Luo Y,Yang J,Jiang Q,Li W,Zhang D,Zhou Z,Cheng Y,Ren Y and He X 2016 Adv.Energy Mater.6 1600007

[5]Luo Y,Yang J,Jiang Q,Li W,Xiao Y,Fu L,Zhang D,Zhou Z and Cheng Y 2015 Nano Energy 18 37

[6]Kucek V,Drasar C,Kasparova J,Plechacek T,Navratil J,Vlcek M and Benes L 2015 J.Appl.Phys.118 125105

[7]Hu C,Peng K,Wang G,Lijie Guo,Wang G and Zhou X 2015 Mater. Res.Soc.Symp.Proc.1735

[8]Carr W D and Morelli D T 2015 J.Alloys Compd.630 277

[9]Zhang J,Liu R,Cheng N,Zhang Y,Yang J,Uher C,Shi X,Chen L and Zhang W 2014 Adv.Mater.26 3848

[10]Cheng N,Liu R,Bai S,Shi X and Chen L 2014 J.Appl.Phys.115 163705

[11]Cui J,Li Y,Du Z,Meng Q and Zhou H 2013 J.Mater.Chem.A 1 677

[12]Liu R,Xi L,Liu H,Shi X,Zhang W and Chen L 2012 Chem.Commun. 48 3818

[13]Kosuga A,Plirdpring T,Higashine R,Matsuzawa M,Kurosaki K and Yamanaka S 2012 Appl.Phys.Lett.100 042108

[14]Plirdpring T,Kurosaki K,Kosuga A,Day T,Firdosy S,Ravi V,Snyder G J,Harnwunggmoung A,Sugahara T,Ohishi Y,Muta H and Yamanaka S 2012 Adv.Mater.24 3622

[15]Yusufu A,Kurosaki K,Kosuga A,Sugahara T,Ohishi Y,Muta H and Yamanaka S 2011 Appl.Phys.Lett.99 061902

[16]Wang H X,Ying P Z,Yang J F,Chen S P and Cui J L 2016 Acta Phys. Sin.65 067201(in Chinese)

[17]Cao B L,Jian J K,Ge B H,Li S M,Wang H,Liu J and Zhao H Z 2017 Chin.Phys.B 26 017202

[18]Biswas K,He J Q,Blum I D,Wu C I,Hogan T P,Seidman D N,Dravid V P and Kanatzidis M G 2012 Nature 489 414

[19]Goldsmid H J 2010 Introduction to Thermoelectricity(Berlin,Heidelberg:Springer-Verlag)pp.37–38

[20]Zhang Y,Wu L H,Zhang J Y,Xing J J and Luo J 2016 Acta Mater.111 202

10.1088/1674-1056/26/9/097201

(Received 8 May 2017;revised manuscript received 10 June 2017;published online 27 July 2017)

?Project supported by the National Natural Science Foundation of China(Nos.51632005 and 51371194)and National Basic Research Program of China(Grant No.2013CB632500).

?Corresponding author.E-mail:junluo@shu.edu.cn

?Corresponding author.E-mail:wqzhang@t.shu.edu.cn

?2017 Chinese Physical Society and IOP Publishing Ltd http://iopscience.iop.org/cpb http://cpb.iphy.ac.cn