南方古生界典型區(qū)塊頁(yè)巖氣勘探潛力評(píng)價(jià)研究進(jìn)展報(bào)告

黃保家 夏斌 盧鴻 蔡?hào)|升 李緒深

摘 要：為評(píng)價(jià)皖南蕪湖區(qū)塊古生界頁(yè)巖氣勘探潛力、優(yōu)選勘探層系，根據(jù)鉆井巖心、露頭巖樣地化、巖石學(xué)分析數(shù)據(jù)及野外調(diào)查等資料，對(duì)該地區(qū)古生界3套富有機(jī)質(zhì)層系的頁(yè)巖氣形成地質(zhì)-地球化學(xué)條件進(jìn)行初步研究，厘定了下?lián)P子蕪湖地區(qū)三套頁(yè)巖的厚度和埋深，對(duì)比研究了三套烴源巖的地球化學(xué)特征，揭示了頁(yè)巖脆性、孔隙類型及其發(fā)育的控制因素，進(jìn)而對(duì)頁(yè)巖氣儲(chǔ)層及勘探潛力進(jìn)行了初步評(píng)價(jià)。從最近鉆探的4口參數(shù)井中采集了365個(gè)頁(yè)巖樣品進(jìn)行TOC和Rock–Eval分析，采用低溫N2吸附和場(chǎng)發(fā)射掃描電鏡（FE-SEM）方法對(duì)其中的57個(gè)樣品進(jìn)行了研究。結(jié)果表明，古生界上奧陶統(tǒng)五峰組-下志留統(tǒng)高家邊組、二疊系（孤峰組+龍?zhí)督M+大隆組）富有機(jī)質(zhì)泥頁(yè)巖層系在區(qū)內(nèi)分布廣、厚度較大、有機(jī)質(zhì)豐富（TOC普遍>2%），且以偏腐殖型為主、熱演化程度較高（Ro=1.3%～3.0%），具有形成頁(yè)巖氣的良好物質(zhì)基礎(chǔ)。它們的礦物基質(zhì)孔和有機(jī)質(zhì)空隙發(fā)育，大小從幾個(gè)納米-上百納米，56柱心樣品總孔隙度主體在2.03%～6.5%之間，其中以介孔和微孔為主；總比表面積為7.19～20.84 m2/g，這些特征與四川盆地志留系龍馬溪組頁(yè)巖儲(chǔ)層特征相似。同時(shí)，其埋深適中且泥頁(yè)巖與硅質(zhì)巖相伴生，利于人工壓裂和勘探開(kāi)發(fā)，有較大勘探潛力。另一方面，古生界寒武統(tǒng)黃柏嶺組富有機(jī)質(zhì)頁(yè)巖有機(jī)質(zhì)豐度高且以腐泥型為主，也有良好的成氣潛力，但因其普遍深埋、成熟度偏高，該區(qū)后期發(fā)生的多期強(qiáng)烈構(gòu)造運(yùn)動(dòng)等因素對(duì)早期形成頁(yè)巖氣的富集及保存可能有一定影響，其勘探潛力有待進(jìn)一步深究。

關(guān)鍵詞：安徽蕪湖地區(qū) 古生界 富有機(jī)質(zhì)泥頁(yè)巖 孔隙結(jié)構(gòu) 頁(yè)巖氣 形成條件 勘探潛力

A Study on Exploration Potential of Paleozoic Shale Gas in the Typical Block，Southern China

Huang Baojia1 Xia Bin2 Lu Hong3 Cai Dongsheng4 Li Xushen1

（1.Zhanjiang Branch，China Offshore oil （China） Co.， Ltd.； 2.Sun Yat-sen University；3.Guangzhou Institute of Geochemistry，Chinese Academy of Sciences；4.CNOOC Research Institute）

Abstract：In order to investigate the exploration potential of the Paleozoic shale gases in the South Anhui， geochemical and reservoir petrologic analysis were made on the representative core samples from the study area. A preliminary study was performed on the geological-geochemical conditions of Paleozoic shale gas formation， by the combination of the data with geological information and outcrop data. it can be found that three sets of organic-rich shale strata， including the lower Cambrian Huangpaling Formation（∈1h）， the upper Ordovician Wufeng Formation（O3w） to the lower Silurian Gaojiabian Formation（S1g），and the Permian Formation（Gufeng Formation（P1g），Longtan Formation （P2l），Dalong Formation （P2d） are developed within Paleozoic. The 365 black shale core samples from 4 wells drilled recently were obtained for TOC and Rock–Eval analysis， and the geochemistry and pore structures of about 57samples were investigated using low pressure N2 adsorption analysis， field emission scanning electron microscopy （FE-SEM） observations. The results show that the O3w- S1g and P1g+P2l+P2d shales with a wide distribution in the studied area have relatively big thickness， high TOC（>2%）， type IIb-III kerogens，high thermal maturity （Ro=1.3%～3.0%）， and high quartz contents. Both mineral matrix and organic matter pores are well developed with pore sizes ranging from several to several hundred nanometers. The total porosity for the 56 samples ranges mainly from 2.03% to 6.5% with majorities of mesoporous and microporous. The total surface area ranges from 7.19～20.84 m2/g.These characteristic are similar to those of Lower Silurian Longmaxi Formation shales in Southern Sichuan Province.Therefore， they could have favorable geological conditions for forming shale gas and relatively big exploration potentia1. On the other hand，∈1h organic-rich shale with type I kerogens should also have relatively great gas generation potential， but its deep burial and over- maturity， especially late multiphase tectonic movement may have some influence on the generation， accumulation and preservation of shale gases within the strata， so its exploration potential of shale gases need further study.

Key Words：South anhui area； Paleozoic； Shale gas； Organic-rich shale； Pore structure； Geological condition； Exploration potential

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