凌錦蘭 趙彥鋒 康珍 姜常義 宋忠寶 趙雙喜 王永剛
1. 長(zhǎng)安大學(xué)地球科學(xué)與資源學(xué)院,西安 7100542. 西部礦產(chǎn)資源與地質(zhì)工程教育部重點(diǎn)實(shí)驗(yàn)室,西安 7100543. 西安地質(zhì)礦產(chǎn)研究所,西安 7100544. 青海省核工業(yè)地質(zhì)局,西寧 8100081.
牛鼻子梁巖體位于柴達(dá)木地塊西北緣。巖體出露面積約8km2,平面形態(tài)呈長(zhǎng)條狀,長(zhǎng)軸方向近東西向。鋯石LA-ICP-MS U-Pb年齡為367.0±2.0Ma。巖體中堆晶結(jié)構(gòu)、堆晶韻律和旋回發(fā)育,屬典型的層狀巖體。巖漿分異充分,巖石類型豐富。主要巖石類型有斜長(zhǎng)二輝橄欖巖、斜長(zhǎng)單輝橄欖巖、角閃二輝橄欖巖、角閃橄欖巖、角閃橄欖二輝巖、角閃二輝巖、橄欖二輝角閃石巖、角閃橄欖輝長(zhǎng)巖、細(xì)粒輝長(zhǎng)巖、似斑狀輝長(zhǎng)巖、暗色輝長(zhǎng)巖、輝長(zhǎng)巖、淡色輝長(zhǎng)巖、石英閃長(zhǎng)巖、英云閃長(zhǎng)巖。巖漿源區(qū)為高鎂拉斑玄武質(zhì)巖漿(MgO=10.8%),主體巖漿結(jié)晶溫度為1100~1178℃。巖漿演化過程中主要發(fā)生了橄欖石的分離結(jié)晶作用,此外還有少量斜長(zhǎng)石的分離結(jié)晶/堆晶作用。野外地質(zhì)觀察、巖石薄片觀察及巖石地球化學(xué)特征表明巖體與圍巖之間發(fā)生了較強(qiáng)的同化混染作用,并且同化混染強(qiáng)度伴隨著巖漿演化過程而逐漸增大。大量的同化混染導(dǎo)致巖石化學(xué)系列從拉斑玄武質(zhì)系列轉(zhuǎn)化為鈣堿性系列。巖漿源區(qū)屬虧損型地幔源區(qū)。巖體形成的構(gòu)造環(huán)境為大陸邊緣裂解環(huán)境。從構(gòu)造環(huán)境、原生巖漿、巖體類型、巖漿分異程度、巖漿含水量、同化混染和橄欖石鎳含量七個(gè)方面來看牛鼻子梁巖體形成鎳銅硫化物礦床的潛力很大。
層狀巖體;巖石成因;成礦條件;牛鼻子梁巖體;柴北緣
柴北緣屬于青藏高原東北緣,區(qū)內(nèi)出露地層齊全,巖漿活動(dòng)頻繁,礦床資源豐富,是地學(xué)研究的熱點(diǎn)地區(qū)之一(Xiaoetal., 2004; Songetal., 2005; 賴少聰?shù)? 1996; 于勝堯等, 2009; 宋術(shù)光等, 2011; 張貴賓和張立飛, 2011)。但前人研究?jī)?nèi)容多圍繞蛇綠巖、榴輝巖、環(huán)斑花崗巖和金伯利巖,而對(duì)幔源巖漿形成的鎂鐵質(zhì)-超鎂鐵質(zhì)侵入巖則鮮見報(bào)導(dǎo)。牛鼻子梁巖體既是由青海省核工業(yè)地質(zhì)局在柴達(dá)木地塊周緣發(fā)現(xiàn)的第一個(gè)賦含鎳銅硫化物的巖體,也是由本文作者在同一區(qū)域首次確認(rèn)的鎂鐵質(zhì)-超鎂鐵質(zhì)層狀雜巖體。本文擬通過詳細(xì)的野外地質(zhì)觀察、巖相學(xué)及全面的巖石地球化學(xué)研究,探討牛鼻子梁巖體的巖石成因并約束其成礦條件及過程。
青海省茫崖牛鼻子梁巖體位于柴達(dá)木地塊西北緣,北距阿爾金南緣斷裂的直線距離約30km(青海省地質(zhì)礦產(chǎn)局,1991)。巖體產(chǎn)出地區(qū)屬鄂博梁古元古宙古陸。構(gòu)造位置處于柴北緣巖漿巖帶中的阿爾金亞帶。區(qū)內(nèi)出露的地層主要是古元古代金水口巖群和第四系。金水口巖群廣泛分布于柴北緣和柴南緣,主要巖石類型包括條帶狀和眼球狀混合巖、黑云母變粒巖、各種片麻巖、斜長(zhǎng)角閃巖、鎂質(zhì)大理巖、二輝麻粒巖等,普遍經(jīng)歷了角閃巖相-麻粒巖相的區(qū)域變質(zhì)作用。受阿爾金和柴北緣陸緣活動(dòng)帶的影響,該區(qū)自元古代以來歷經(jīng)多次構(gòu)造-巖漿活動(dòng),遭受了多次強(qiáng)烈改造,構(gòu)造形跡復(fù)雜,斷裂以北東東向、近東西向和北西向?yàn)橹鳌?/p>
牛鼻子梁巖體的出露面積約8km2,巖體平面形態(tài)呈長(zhǎng)條狀,長(zhǎng)軸方向近東西向,與區(qū)域構(gòu)造線方向一致(圖1)。根據(jù)巖性的不同和斷裂對(duì)巖體的切割情況,我們將巖體分成Ⅰ、Ⅱ、Ⅲ三個(gè)區(qū)塊。巖體的直接圍巖為古元古代金水口巖群片麻巖和大理巖。二者為侵入接觸關(guān)系,在巖體中多處發(fā)現(xiàn)有圍巖捕虜體及殘留頂蓋。圍巖捕虜體多為透鏡狀,長(zhǎng)軸方向可達(dá)50~100cm;此外,在薄片中經(jīng)常見到毫米到厘米級(jí)的捕虜體,巖性為金水口巖群片麻巖、變粒巖、片巖及大理巖等。后期的石英閃長(zhǎng)巖、花崗巖巖枝和巖脈沿北側(cè)和南側(cè)的局部部位侵入到牛鼻子梁巖體和金水口巖群中。這些中酸性侵入巖和斷裂構(gòu)造對(duì)牛鼻子梁巖體造成了很大的破壞作用。
牛鼻子梁巖體普遍具有層狀和紋層狀構(gòu)造(圖2a-c),紋層即為堆晶巖中能識(shí)別的最小單元層;層理是以均勻漸變性質(zhì)為特征的連續(xù)似席狀堆晶巖。根據(jù)Wylline(1967)對(duì)層理的進(jìn)一步劃分,我們又可以將牛鼻子梁巖體的層理分為同成分層、漸變層、粒序?qū)?、化學(xué)層等。與上述層理相對(duì)應(yīng),牛鼻子梁巖體的層理面可分為相界面、比率界面和結(jié)構(gòu)界面三種。相界面是指以某種堆晶礦物的出現(xiàn)或消失為特點(diǎn)的一種界面(圖2d, e);比率界面是指以兩種堆晶礦物的比率發(fā)生改變?yōu)樘攸c(diǎn)的一種界面(圖2f);結(jié)構(gòu)界面是指以某種堆晶礦物的物理性質(zhì)(如大小、形態(tài)等)突然變化為特點(diǎn)的一種界面(圖2g)。相界面主要出現(xiàn)在鎂鐵質(zhì)巖石與超鎂鐵質(zhì)巖石接觸面上,比率界面和結(jié)構(gòu)界面主要出現(xiàn)在不同的鎂鐵質(zhì)巖層之間。
大量的實(shí)測(cè)地質(zhì)剖面和鉆孔資料表明,牛鼻子梁巖體具有清晰的垂直分帶(圖3)。在現(xiàn)有鉆孔控制的深度范圍內(nèi),可以將該巖體的堆晶層理劃分為下部、中部和上部層序。Ⅰ號(hào)區(qū)塊(四號(hào)剖面和ZK0401)代表下部層序,常見的堆晶韻律是角閃二輝橄欖巖-角閃橄欖二輝巖-角閃橄欖輝長(zhǎng)巖,以橄欖巖相和輝石巖相為主。Ⅱ號(hào)區(qū)塊(五號(hào)剖面)代表中部層序,常見的堆晶韻律是角閃二輝橄欖巖-角閃橄欖輝長(zhǎng)巖-輝長(zhǎng)巖-淡色輝長(zhǎng)巖,超鎂鐵質(zhì)巖石與鎂鐵質(zhì)巖石并存,后者多于前者。Ⅲ號(hào)區(qū)塊(六號(hào)剖面和ZK100-1)代表上部層序,堆晶韻律表現(xiàn)為橄欖二輝角閃石巖/二輝巖-暗色輝長(zhǎng)巖-輝長(zhǎng)巖-石英閃長(zhǎng)巖/英云閃長(zhǎng)巖,以輝長(zhǎng)巖為主。從下部層序向上部層序,超鎂鐵質(zhì)巖石所占比例逐漸減少,而鎂鐵質(zhì)巖石逐漸增多。而且,在上部層序中不但出現(xiàn)了石英閃長(zhǎng)巖和英云閃長(zhǎng)巖,還有相當(dāng)數(shù)量的角閃石巖,既證明巖漿經(jīng)歷了充分的分異演化過程,還證明在巖漿演化的晚期階段巖漿富水。根據(jù)下、中、上部堆晶層序的總體特征,我們判斷,它們代表了同一堆晶旋回。
圖1 牛鼻子梁巖體大地構(gòu)造位置及地質(zhì)略圖Fig.1 Tectonic location and sketch geological map of the Niubiziliang intrusion
圖2 層狀和紋層狀構(gòu)造及層理面(a)-輝長(zhǎng)巖與暗色輝長(zhǎng)巖互層;(b)-淡色輝長(zhǎng)巖與輝長(zhǎng)巖紋層;(c)-橄欖巖中輝石單礦物紋層;(d)-輝長(zhǎng)巖與橄欖巖的相界面,以橄欖石的消失為特點(diǎn);(e)-輝長(zhǎng)巖與輝石巖的相界面,以斜長(zhǎng)石的出現(xiàn)為特點(diǎn);(f)-輝長(zhǎng)巖與暗色輝長(zhǎng)巖的比率界面,以輝石與斜長(zhǎng)石的比率發(fā)生改變?yōu)樘攸c(diǎn);(g)-似斑狀輝長(zhǎng)巖與輝長(zhǎng)巖的結(jié)構(gòu)界面Fig.2 Layers, laminas and horizons in cumulates(a)-layers of gabbro and melagabbro; (b)-laminas of leucogabbro and gabbro; (c)-laminas of peridotite and pyroxenite; (d)-phase contact of gabbro and peridotite marked by the disappearance of olive; (e)-phase contact of gabbro and pyroxentie marked by the appearance of plagioclase; (f)-ratio contact of gabbro and melagabbro marked by a sharp change in the proportions of pyroxene and plagioclase; (g)-form contact of porphyaceous gabbro and gabbro
圖3 野外剖面與鉆孔巖芯柱狀圖Fig.3 Columnar section of outcrops and drills
本文超鎂鐵質(zhì)巖石采用IUGS火成巖分類學(xué)分委會(huì)推薦的分類方案(1991)。由此確定的橄欖巖相巖石類型有:斜長(zhǎng)二輝橄欖巖、斜長(zhǎng)單輝橄欖巖、角閃二輝橄欖巖、角閃橄欖巖。這些巖石最主要的結(jié)構(gòu)類型是正堆晶結(jié)構(gòu)和包含結(jié)構(gòu)。橄欖石全部為堆晶相;斜長(zhǎng)石部分為堆晶相,部分為填隙相;單斜輝石、斜方輝石及褐色角閃石全部為填隙相。最常見的包含結(jié)構(gòu)是包橄結(jié)構(gòu)和含長(zhǎng)結(jié)構(gòu),其次是角閃石包裹輝石。包橄結(jié)構(gòu)主要是橄欖石包裹于單斜輝石、斜方輝石和褐色角閃石中,也有少量包裹于斜長(zhǎng)石中;含長(zhǎng)結(jié)構(gòu)表現(xiàn)為斜長(zhǎng)石包裹于單斜輝石、斜方輝石和褐色角閃石中。橄欖石呈渾圓狀;堆晶相的斜長(zhǎng)石呈板條狀,填隙相的斜長(zhǎng)石多呈他形;單斜輝石、斜方輝石和褐色角閃石均呈他形,局部結(jié)晶粗大,包裹多個(gè)細(xì)小的橄欖石或斜長(zhǎng)石。副礦物有尖晶石和磁鐵礦。
輝石巖相包括角閃橄欖二輝巖、角閃二輝巖。角閃橄欖二輝巖的結(jié)構(gòu)類型有正堆晶結(jié)構(gòu)和包含結(jié)構(gòu),橄欖石為堆晶相,單斜輝石、斜方輝石、褐色角閃石和斜長(zhǎng)石為填隙相。包含結(jié)構(gòu)主要是包橄結(jié)構(gòu),其次為褐色角閃石包裹輝石和斜長(zhǎng)石。橄欖石呈渾圓狀,輝石半自形短柱狀-他形,褐色角閃石和斜長(zhǎng)石呈他形。角閃二輝巖為中粒結(jié)構(gòu),主要由單斜輝石、斜方輝石、褐色角閃石和石英組成。輝石自形短柱狀,角閃石長(zhǎng)柱狀或他形;石英呈他形,局部含量較高,是巖漿晚期熱液交代的產(chǎn)物。
橄欖二輝角閃石巖的結(jié)構(gòu)類型有正堆晶結(jié)構(gòu)、包含結(jié)構(gòu)、粗粒結(jié)構(gòu)。褐色角閃石含量60%~75%。堆晶相主要為橄欖石,也有少量的斜方輝石;填隙相為斜方輝石、單斜輝石和角閃石。包含結(jié)構(gòu)主要是褐色角閃石包裹橄欖石、斜方輝石。橄欖石呈渾圓狀;褐色角閃石呈他形,粒度粗大,包裹多個(gè)橄欖石顆粒;輝石呈半自形短柱狀-他形粒狀。
在超鎂鐵質(zhì)巖石中,主要蝕變類型有:橄欖石蛇紋石化、滑石化,并析出塵狀磁鐵礦;斜方輝石蛇紋石化、滑石化;單斜輝石次閃石化、綠泥石化;褐色角閃石陽(yáng)起石化、黑云母化和綠泥石化;斜長(zhǎng)石鈉黝簾石化。
輝長(zhǎng)巖類中除細(xì)粒輝長(zhǎng)巖和似斑狀輝長(zhǎng)巖外,其他均具有正堆晶結(jié)構(gòu)。暗色輝長(zhǎng)巖中堆晶相為單斜輝石,斜長(zhǎng)石和石英為填隙相;輝長(zhǎng)巖中斜長(zhǎng)石為堆晶相,單斜輝石、褐色角閃石和石英為填隙相。淡色輝長(zhǎng)巖中的堆晶相既可以是單斜輝石也可以是斜長(zhǎng)石,填隙相包括斜長(zhǎng)石或單斜輝石、褐色角閃石和石英。細(xì)粒輝長(zhǎng)巖具有輝長(zhǎng)結(jié)構(gòu);似斑狀輝長(zhǎng)巖具有斑狀結(jié)構(gòu),斑晶主要為單斜輝石,也有少量斜長(zhǎng)石,基質(zhì)主要是細(xì)粒單斜輝石、斜長(zhǎng)石及石英。除角閃橄欖輝長(zhǎng)巖外,所有的鎂鐵質(zhì)巖石中均含有石英。副礦物有鈦鐵礦、磷灰石和磁鐵礦。
石英閃長(zhǎng)巖為半自形粒狀結(jié)構(gòu),巖石主要由斜長(zhǎng)石(70%~83%)、石英(10%~14%)和角閃石(7%~15%)組成。斜長(zhǎng)石,半自形,粒徑0.2~4mm,聚片雙晶發(fā)育,可見環(huán)帶,強(qiáng)烈鈉黝簾石化、絹云母化;角閃石,半自形,已完全被陽(yáng)起石、黑云母和綠泥石交代;石英呈他形填隙狀。
英云閃長(zhǎng)巖中主要為花崗結(jié)構(gòu)及石英和斜長(zhǎng)石組成的蠕蟲結(jié)構(gòu)。巖石主要由斜長(zhǎng)石 (60%~72%)、石英(25%~30%)及少量的鉀長(zhǎng)石(0%~7%)和黑云母(約3%)組成。黑云母,自形,粒徑0.2~1.2mm,部分被綠泥石交代;斜長(zhǎng)石,呈自形板狀,粒徑0.2~1.5m,雙晶發(fā)育,絹云母化強(qiáng);石英呈他形充填狀。
圖4 牛鼻子梁巖體輝長(zhǎng)巖的LA-ICP-MS鋯石206Pb/238U加權(quán)平均年齡及206Pb/238U-207Pb/235U諧和年齡圖Fig.4 206Pb/238U weighted average ages and 206Pb/238U-207Pb/235U concordia age of LA-ICP-MS zircon U-Pb dating of gabbro from Niubiziliang intrusion
鋯石LA-ICP-MS U-Pb年齡分析在北京大學(xué)造山帶與地殼演化教育部重點(diǎn)實(shí)驗(yàn)室采用Agilent 7500a型四級(jí)桿等離子體質(zhì)譜儀測(cè)定。主要造巖礦物化學(xué)組成在長(zhǎng)安大學(xué)西部礦產(chǎn)資源與地質(zhì)工程教育部重點(diǎn)實(shí)驗(yàn)室采用JXI-8100型電子探針分析,加速電壓15kV,束電流1.0×10-8A,束斑直徑1μm。主量元素分析在西北大學(xué)大陸動(dòng)力學(xué)實(shí)驗(yàn)室采用3080E型X-射線熒光光譜儀分析,XRF熔片法按國(guó)家標(biāo)準(zhǔn)GB/T 14506.28—1993。微量元素在長(zhǎng)安大學(xué)西部礦產(chǎn)資源與地質(zhì)工程教育部重點(diǎn)實(shí)驗(yàn)室采用美國(guó)X7型ICP-MS測(cè)定。Nd、Sr和Pb同位素比值測(cè)試在中國(guó)科學(xué)院廣州地球化學(xué)研究所完成。Nd、Sr同位素分析儀器為Micromass Isoprobe型多接收器等離子體質(zhì)譜儀。Pb同位素所用儀器為VG354熱電離質(zhì)譜儀。
本文作者采集了Ⅲ區(qū)輝長(zhǎng)巖樣品進(jìn)行測(cè)試。所選鋯石振蕩環(huán)帶發(fā)育,均為巖漿成因鋯石。對(duì)該樣品共做15個(gè)鋯石分析點(diǎn),其U含量為51×10-6~259×10-6,Th含量為15×10-6~246×10-6,Th/U比值為0.29~0.95,平均為0.66,為典型巖漿成因鋯石Th/U比(Belousovaetal., 2002)。206Pb/238U加權(quán)平均年齡(367.2±2.2Ma)與諧和線年齡(367.0±2.0Ma)一致 (表1、 圖4),代表了牛鼻子梁巖體的侵位結(jié)晶年齡,證明該巖體形成于晚泥盆世。
表1牛鼻子梁輝長(zhǎng)巖LA-ICP-MS鋯石U-Pb數(shù)據(jù)
Table 1Zircon LA-ICP-MS U-Pb data of gabbro in Niubiziliang
測(cè)點(diǎn)號(hào)Th(×10-6)U(×10-6)ThU207Pb206Pb207Pb235U206Pb238U208Pb232Th207Pb206Pb(Ma)±1σ207Pb235U(Ma)±1σ206Pb238U(Ma)±1σ208Pb232Th(Ma)±1σ157.44117.310.490.05460.43750.05810.019539744.43696.23644.23916.9285.21118.510.720.05480.44300.05870.017840245.73726.43684.23565.8366.86105.670.630.05220.42650.05930.0181295115.436115.53716.836315.14142.09192.890.740.05400.43080.05790.017737267.13649.13634.93558.35106.15145.150.730.05350.42610.05780.0182349148.436020.23628.336518.76174.97192.20.910.05150.42490.05990.018226169.73609.23755.03658.07246.61259.350.950.05400.43670.05870.017737280.336811.03685.43568.9856.69101.780.560.05430.43100.05760.0180383132.736418.23617.536018.9915.1551.480.750.04930.40710.06000.0131160433.234760.637621.626388.61030.4669.110.290.05500.44110.05820.0190411115.137116.13656.738019.41151.2488.730.440.05580.44930.05850.016744365.43779.23664.93349.01266.07111.190.580.05390.44020.05920.017636856.03707.73714.63537.713114.43156.320.590.05370.43030.05820.018035742.03635.73654.13605.314162.16218.150.730.05530.45160.05920.017942651.23787.33714.53586.615110.18147.040.740.05560.44270.05780.0189438155.237221.93628.837820.1
表2各類巖石中橄欖石電子探針數(shù)據(jù)(wt%)
Table 2EPMA results (wt%) of olivine from the Niubiziliang intrusion
樣品號(hào)巖性SiO2FeOMnOAl2O3CaOTiO2MgOCr2O3NiONa2OP2O5K2OTotal組成種屬401-G1-1斜長(zhǎng)二輝橄欖巖39.3316.960.300.030.010.0643.450.020.140.05--100.34Fo82Fa18401-G1-2斜長(zhǎng)二輝橄欖巖39.5616.590.23-0.010.0643.550.040.100.010.030.01100.19Fo82Fa18401G1-4斜長(zhǎng)二輝橄欖巖39.2615.090.30---44.810.040.13-0.040.0099.65Fo84Fa16401-G4-1角閃二輝橄欖巖39.3016.430.290.050.03-44.22-0.06---100.38Fo83Fa17401-G4-2角閃二輝橄欖巖39.3616.110.16--0.0243.950.030.140.000.06-99.84Fo83Fa17401-G4-3角閃二輝橄欖巖39.9515.460.310.060.040.0145.20-0.170.030.000.01101.23Fo84Fa16401-G4-4角閃二輝橄欖巖40.6615.080.320.272.04-42.300.050.120.00-0.00100.85Fo83Fa17II4-7-4橄欖二輝巖38.9617.390.210.060.020.0142.490.100.11-0.01-99.35Fo81Fa19II4-7-6橄欖二輝巖39.2817.180.23--0.0143.640.120.090.02--100.57Fo82Fa18II5-16-8角閃橄欖輝長(zhǎng)巖39.5316.400.27--0.0444.06-0.17--0.00100.47Fo83Fa17II5-18-3角閃橄欖輝長(zhǎng)巖39.4117.410.28-0.020.0543.440.010.190.01--100.80Fo82Fa18II5-18-7角閃橄欖輝長(zhǎng)巖39.7815.790.260.040.020.0144.870.050.160.000.020.00101.01Fo84Fa16II5-4-1角閃橄欖巖39.8516.590.320.00--44.860.040.200.040.01-101.91Fo83Fa17II5-5-5角閃橄欖輝長(zhǎng)巖38.8619.020.24-0.030.0242.470.080.140.03--100.88Fo80Fa20II5-5-6角閃橄欖輝長(zhǎng)巖39.0118.350.280.000.01-42.590.010.17---100.42Fo81Fa19II5-6-3角閃橄欖輝長(zhǎng)巖39.0419.360.30--0.0542.470.030.140.040.02-101.45Fo80Fa20II5-6-5角閃橄欖輝長(zhǎng)巖39.2019.210.260.04--41.480.020.130.01-0.01100.35Fo79Fa21II5-9-1角閃橄欖輝長(zhǎng)巖39.1318.350.28-0.00-42.21-0.23-0.04-100.24Fo80Fa20II5-9-13角閃橄欖輝長(zhǎng)巖39.0417.770.32---41.590.020.180.02-0.0198.95Fo81Fa19II6-7-7橄欖輝石角閃石巖38.7619.870.33---40.810.030.150.04-0.0299.99Fo79Fa21II6-7-8橄欖輝石角閃石巖39.4818.240.19-0.020.0242.560.010.160.06--100.73Fo81Fa19貴橄欖石
斜長(zhǎng)二輝橄欖巖、角閃二輝橄欖巖和角閃橄欖巖中橄欖石的Fo分子為82~84,平均值為83.0。橄欖二輝巖中橄欖石的Fo分子為81~82,平均值為81.5。橄欖輝長(zhǎng)巖中橄欖石的Fo分子為79~84,平均值為81.2。橄欖二輝角閃石巖中橄欖石的Fo分子為79~81,平均值為80.0(表2)。各種巖相中的橄欖石均為貴橄欖石,F(xiàn)o分子介于79~84之間,變化范圍很小。盡管如此,還是顯示了從橄欖巖相→橄欖二輝巖→橄欖輝長(zhǎng)巖→橄欖二輝角閃石巖,隨著巖漿的演化,F(xiàn)o分子總體上呈現(xiàn)緩慢而逐漸降低的趨勢(shì)。
圖5 巖石化學(xué)系列分類圖Fig.5 Classification of rock chemical series
斜方輝石En=80~84,均為古銅輝石,在不同的巖石類型之間En端元組分沒有明顯的變化規(guī)律(表3)。在橄欖巖相、橄欖二輝巖和橄欖輝長(zhǎng)巖中單斜輝石主要是透輝石和頑透輝石,而在輝長(zhǎng)巖相中主要是普通輝石。
斜長(zhǎng)石的An牌號(hào)變化范圍較大(17~77),從更長(zhǎng)石到倍長(zhǎng)石均有(表4)。斜長(zhǎng)二輝橄欖巖中主要為倍長(zhǎng)石和拉長(zhǎng)石,橄欖二輝巖中為拉長(zhǎng)石,角閃橄欖輝長(zhǎng)巖中主要為拉長(zhǎng)石,輝長(zhǎng)巖中主要為拉長(zhǎng)石,此外有少量的中長(zhǎng)石,淡色輝長(zhǎng)巖中主要為拉長(zhǎng)石和中長(zhǎng)石。英云閃長(zhǎng)巖中主要為中長(zhǎng)石和更長(zhǎng)石,有少量的拉長(zhǎng)石。其中部分斜長(zhǎng)石環(huán)帶明顯,從邊緣-中心-邊緣依次為:更長(zhǎng)石-中長(zhǎng)石-拉長(zhǎng)石-更長(zhǎng)石,屬于正環(huán)帶;另一個(gè)環(huán)帶邊緣-中心-邊緣為:中長(zhǎng)石-拉長(zhǎng)石-更長(zhǎng)石-拉長(zhǎng)石-更長(zhǎng)石,屬韻律性環(huán)帶。英云閃長(zhǎng)巖中含有拉長(zhǎng)石和中長(zhǎng)石,從礦物學(xué)角度反映了該巖石是鎂鐵質(zhì)巖漿分異演化的產(chǎn)物。
探針分析的原生角閃石在單偏光鏡下均呈褐色。采用O=23的陰離子法計(jì)算其晶體化學(xué)式,主要屬鈣質(zhì)閃石組的鈦角閃石、鈣鎂閃石普通角閃石、韭閃石、韭閃普通角閃石(表5)。所有Si/(Si+Al+Ti)均小于0.765,Al2O3含量均大于10%,均是幔源巖漿中結(jié)晶的角閃石(姜常義和安三元,1984)。
5.3.1主量元素
所有樣品的SiO2含量介于36.17%~72.37%;其中3件樣品的SiO2含量為62.48%~72.37%,屬于中酸性巖類;其余樣品的SiO2含量為36.17%~53.01%,屬于基性-超基性巖類(表6)。所有超基性巖類樣品的m/f值(3.84~4.90)都小于6.5而大于2.5,屬于鐵質(zhì)超基性巖類。所有樣品的Mg#值為55~83,變化范圍較大。在單斜輝石的SiO2-Al2O3圖解(圖5a)中,幾乎所有的單斜輝石都位于亞堿性巖區(qū),表明其原生巖漿屬于亞堿性系列(Le Bas, 1962)。在單斜輝石AlⅣ-Si圖(圖5b)上,所有樣品均位于拉斑玄武巖區(qū)(Kushiro, 1960)。需要說明的是,這里的拉斑玄武巖系列是有別于無似長(zhǎng)石堿性巖和有似長(zhǎng)石堿性巖的化學(xué)系列,應(yīng)該將其理解為亞堿性玄武巖系列。在Miyashiro(1974)針對(duì)火山巖所做的FeOT/MgO-SiO2、FeOT/MgO-FeO圖解(圖5c,d)中,大部分超鎂鐵質(zhì)巖石樣品位于拉斑玄武巖系列及拉斑玄武巖與鈣堿性系列的過渡帶,而鎂鐵質(zhì)巖石樣品均投影于鈣堿性系列區(qū),屬跨越型趨勢(shì)。
5.3.2稀土與微量元素
橄欖巖的∑REE=16.02×10-6~42.50×10-6,另有1件樣品(Ⅱ5-4)的∑REE=51.35×10-6,該件樣品的Mg#(0.79)和m/f值(3.84)低于其他樣品,而SiO2(44.47%)高于其他樣品,說明該件樣品與其他樣品稀土元素總量的差異應(yīng)該是含堆晶相橄欖石較少所致。其余巖石的∑REE=17.30×10-6~83.77×10-6,另有輝長(zhǎng)巖的稀土元素總量較高(111.4×10-6),該件輝長(zhǎng)巖的Mg#(0.55)和m/f值(1.24)均明顯低于同類巖石的相應(yīng)數(shù)值,說明他們之間稀土元素總量的差異應(yīng)該與其巖漿演化程度有關(guān)。所有樣品的(La/Yb)N=2.65~9.85,(La/Sm)N=1.47~4.01,(Gd/Yb)N=1.61~2.57。輕重稀土元素之間及輕、重稀土元素內(nèi)部分餾均較強(qiáng),配分曲線屬輕稀土元素富集型。除英云閃長(zhǎng)巖外,所有的樣品δEu=0.79~1.35,未顯示銪異?;蜾B異常不明顯。2件英云閃長(zhǎng)巖1件表現(xiàn)為明顯的正銪異常(δEu=2.43),另1件表現(xiàn)為明顯的負(fù)銪異常(δEu=0.59)。
表6牛鼻子梁巖體各類巖石主量元素(wt%)和微量元素(×10-6)分析數(shù)據(jù)
Table 6Major (wt%) and trace element (×10-6) compositions of the Niubiziliang intrusion
樣品號(hào)401-G1-4401-G5401-G1-7401-G3401-G4-2401-G4-4II5-4II5-7II4-7II5-6II5-9II5-8巖性斜長(zhǎng)二輝橄欖巖角閃橄欖巖角閃二輝橄欖巖橄欖二輝巖角閃橄欖輝長(zhǎng)巖細(xì)粒輝長(zhǎng)巖SiO240.0440.2541.3536.1740.9440.2044.4739.4640.6939.9142.3951.14TiO20.550.50.770.370.340.470.720.400.420.440.540.89Al2O36.196.008.015.494.845.4412.335.606.525.838.4015.55Fe2O313.6413.3911.9111.8513.2813.6210.4612.4213.1812.6412.888.29MnO0.160.170.130.160.160.170.140.150.160.140.160.13MgO28.9329.1724.1527.5831.7931.0020.0930.4327.8529.8825.888.84CaO3.383.274.972.872.833.027.012.833.923.124.868.31Na2O0.750.900.690.330.720.811.740.770.890.431.524.13K2O0.260.250.330.250.360.260.360.250.260.270.230.53P2O50.110.090.160.070.060.090.170.070.060.070.090.14LOI5.595.547.0614.414.384.462.467.335.826.882.662.02TOTAL99.6099.5399.5399.5599.7099.5499.9599.7199.7799.6199.6199.97Mg#0.810.810.80.820.830.820.790.830.810.830.80.68m/f4.244.364.064.654.794.553.844.94.234.734.022.13Sc17.4619.220.3718.4218.8416.0215.8617.4516.0718.3515.8227.15V71.4667.786.2356.3358.5967.2283.1655.3871.5160.9568.01131.4Cr1894179813651869224121879181457182613991500378Co130.7120.7105.7123.5125.613790.05133.5126.8130.9116.447.58Ni395.4793304.2320735.1361273.1495.3354.2513.6396.968.45Cu229.8171.570.0871.6683.02160.573.0360.18127.195.5496.7656.97Zn83.8976.5375.7876.0578.2380.8473.0575.8879.9579.3380.0564.48Ga6.676.328.355.595.466.1910.435.866.545.957.6514.67Rb10.136.8314.249.517.689.312.578.658.088.37.3816.47Sr141.8127.9206.611786.89113.3220.165.76115.9107.1153.5302.2Y5.16.599.344.84.686.148.965.715.765.856.9415.36Zr38.9550.6450.2934.6431.1942.4479.1740.233.7337.9545.95106.7Nb5.482.015.261.421.261.997.721.011.451.363.214.04Cd0.140.160.150.110.080.150.150.10.140.190.140.25In0.030.020.030.020.020.020.030.020.020.020.020.04Ba49.6629.7835.5644.0845.0432.4239.4118.8229.8327.7725.15106.7La5.73.086.922.282.213.039.4922.362.33.678.89Ce11.777.2815.245.295.057.0419.714.885.575.418.3119.8Pr1.410.971.960.710.690.952.370.70.770.761.112.51Nd5.994.468.693.33.274.3310.073.333.63.545.1411.32Sm1.221.111.970.780.821.032.10.880.920.921.192.59Eu0.460.40.740.270.290.370.740.330.370.350.450.97Gd1.391.312.240.971.011.252.321.131.141.151.53.15Tb0.190.210.320.150.150.180.310.180.170.180.230.48Dy1.071.271.880.910.911.241.821.081.11.071.343.04Ho0.210.260.370.190.180.230.350.210.220.220.270.6Er0.560.741.040.540.540.691.010.630.640.620.781.71Tm0.070.10.140.080.070.10.140.090.090.10.110.24Yb0.450.550.860.480.410.550.80.540.560.590.671.42Lu0.070.110.130.080.080.10.130.090.090.10.110.25Hf0.8711.130.690.740.871.610.840.730.760.982.3Ta0.320.160.30.10.110.140.450.070.10.090.180.26Pb2.682.822.541.61.441.521.871.082.931.551.456.41Bi0.10.080.060.050.10.060.070.030.10.270.060.06Th0.810.6310.450.620.51.170.440.340.420.622.79U0.210.20.290.120.230.140.350.110.130.130.180.61∑REE30.5621.8442.5016.0215.6721.0951.3516.0717.6117.3024.8556.98δEu1.071.031.080.940.991.001.021.021.101.051.031.04(La/Sm)N3.011.792.271.891.751.892.921.471.651.612.02.21(La/Yb)N9.174.045.83.43.873.958.552.653.02.83.934.49(Gd/Yb)N2.571.982.161.662.031.882.411.721.671.611.851.83Nb/U25.8310.117.9512.035.5813.8122.369.0711.3410.6918.146.58
續(xù)表6
Continued Table 6
樣品號(hào)II6-5II6-7II6-9II5-1II5-15II6-10II6-3II5-14II6-1II6-2II6-4II6-8巖性橄欖二輝角閃石巖輝長(zhǎng)巖似斑狀輝長(zhǎng)巖淡色輝長(zhǎng)巖石英閃長(zhǎng)巖英云閃長(zhǎng)巖SiO245.5546.9247.4749.9750.6048.8852.0652.0453.0162.4870.9572.37TiO20.380.470.450.811.290.430.660.760.760.660.180.19Al2O37.027.087.3317.3116.9215.8611.5315.8115.7216.3414.5514.22Fe2O39.689.769.848.49.756.448.088.77.824.911.781.7MnO0.130.130.130.130.150.100.130.150.140.090.050.04MgO24.4722.1721.518.216.0311.2512.78.037.263.181.441.48CaO5.828.178.159.499.7211.288.39.089.584.242.573.48Na2O1.041.111.232.953.491.512.293.022.874.595.344.53K2O0.440.420.50.40.541.281.120.280.820.921.160.92P2O50.080.080.080.110.280.080.130.090.130.160.050.06LOI4.913.252.832.211.172.422.842.011.852.391.470.86TOTAL99.5299.5699.5299.9999.9499.5399.8499.9799.9699.9699.5499.85Mg#0.830.820.810.660.550.780.760.650.650.560.620.64m/f5.064.544.371.951.243.493.141.851.861.31.621.74Sc21.731.5532.3425.9526.7629.2127.6832.8129.0414.8911.3711.09V92.79128.8121.6127.7205.4120.6149.1205.2147.875.4214.9516.41Cr24251933163737110464510199960804344Co76.1179.8782.0643.7127.9142.848.4639.4135.3819.518.88.79Ni619263.6251.643.7823.9981.51117.254.3121.0326.5915.1517.3Cu19.2838.7741.6648.6321.7947.7236.2639.0731.7131.8313.4513.66Zn64.7263.3769.7961.295.7946.7366.7261.866.9563.1820.4123.61Ga7.197.87.9414.3619.0812.7313.8914.8816.5315.8811.510.99Rb9.7211.3515.2913.0215.4363.3835.868.9622.8219.9833.8936.52Sr165.4166179.6337501.8424.5277.1321.5634.7411.5346.5409.7Y5.817.787.8613.6824.528.3716.2811.2813.7411.6811.163.7Zr38.6140.8344.3581.2386.0448.3378.0156.0353.79177.8147.978.59Nb1.351.521.623.219.811.584.414.243.423.935.724.27Cd0.110.110.130.20.270.110.210.210.150.280.210.13In0.030.030.030.040.070.030.040.040.040.030.020.01Ba61.9459.3380.878.02124.7134.2229.472.31187.6205.3348.5227.6La3.993.534.235.9516.954.0210.216.5311.58.5615.874.18Ce8.478.79.4413.9340.459.3725.214.0127.923.5138.198.19Pr1.111.181.231.875.381.313.431.793.572.613.750.8Nd5.025.695.728.4923.546.1115.67.9415.7111.4614.633.12Sm1.221.421.452.115.131.543.421.913.382.522.610.67Eu0.390.470.510.871.550.620.910.931.090.810.520.59Gd1.371.641.632.655.591.83.562.343.472.772.770.82Tb0.190.240.240.420.810.260.520.370.480.380.350.11Dy1.161.421.472.664.751.572.932.282.712.211.910.62Ho0.240.290.290.531.010.330.590.480.540.450.390.13Er0.660.830.861.542.950.911.711.351.531.281.220.39Tm0.090.120.120.220.40.130.250.190.220.180.180.06Yb0.540.710.711.362.510.721.431.091.261.031.160.35Lu0.090.110.110.220.390.120.250.180.210.170.220.07Hf0.941.011.071.882.521.12.221.371.573.753.971.88Ta0.090.090.110.230.580.10.260.270.250.340.810.27Pb2.251.822.543.656.42.296.212.826.789.715.3513.51Bi0.070.050.050.120.060.030.070.050.080.070.050.02Th1.40.842.381.461.610.681.481.382.982.9612.851.24U0.60.470.910.340.780.280.470.420.880.951.30.55∑REE24.5426.3528.0042.81111.428.869.9941.3873.5757.9383.7720.10δEu0.910.941.011.130.881.130.791.350.960.940.592.43(La/Sm)N2.121.61.881.822.131.681.932.212.22.193.924.01(La/Yb)N5.323.564.253.144.854.015.144.286.575.989.858.52(Gd/Yb)N2.111.911.881.611.842.072.061.772.292.231.981.92Nb/U2.243.211.779.4912.655.769.3310.143.884.124.427.82
注:Mg#與m/f值由主量元素百分化后計(jì)算所得:Mg#=(MgO/40)/(MgO/40+0.8998×Fe2O3T/72),m/f=(MgO/40)/(0.8998×Fe2O3T/72);計(jì)算(La/Sm)N、(La/Yb)N、(Gd/Yb)N、δEu的球粒隕石標(biāo)準(zhǔn)化值據(jù)Sun and McDonough (1989)
圖6 球粒隕石標(biāo)準(zhǔn)化稀土元素配分圖和原始地幔標(biāo)準(zhǔn)化蛛網(wǎng)圖(標(biāo)準(zhǔn)化值據(jù)Sun and McDonough, 1989)Fig.6 Chondrite-normalized REE patterns and PM-normalized trace elements spider diagrams (normalization values after Sun and McDonough, 1989)
各種巖石的原始地幔標(biāo)準(zhǔn)化微量元素配分曲線(圖6)具有相同或相近的特征。配分曲線總體平滑且低緩,沒有特別富集的元素。稀土元素和大多數(shù)高場(chǎng)強(qiáng)元素的原始地幔標(biāo)準(zhǔn)化值多低于10,而大離子親石元素的標(biāo)準(zhǔn)化值多大于10。與稀土元素總量的差異一樣,同類巖石微量元素配分曲線的一些細(xì)微差異也應(yīng)該與巖漿演化程度有關(guān)。大多數(shù)樣品有弱到明顯的負(fù)Nb異常,Ta也有同樣的趨勢(shì),但不如Nb明顯??傮w趨勢(shì)是,以橄欖巖相到淡色輝長(zhǎng)巖、石英閃長(zhǎng)巖和英云閃長(zhǎng)巖,Nb(Ta)的負(fù)異常逐漸顯著。這種變化趨勢(shì)應(yīng)該與巖漿被金水口巖群混染有關(guān)(詳見后述)。部分輝長(zhǎng)巖相巖石和石英閃長(zhǎng)巖、英云閃長(zhǎng)巖有不同程度的P、Ti負(fù)異常,而其它巖石則無此特征。也就是說,P、Ti負(fù)異常只出現(xiàn)在巖漿演化的晚期階段,而非巖漿的固有特征。這種情況應(yīng)當(dāng)與磷灰石和尖晶石的結(jié)晶作用有關(guān),這兩種礦物的分離結(jié)晶導(dǎo)致演化的巖漿虧損P和Ti。
5.3.3同位素
Nd-Sr-Pb同位素分析數(shù)據(jù)見表7。采用巖體中輝長(zhǎng)巖相的鋯石LA-ICP-MS U-Pb諧和年齡367Ma,得到εNd(t)=+5.02~-1.52, (87Sr/86Sr)i=0.7035~0.7062。斜長(zhǎng)二輝橄欖巖樣品的Nd、Sr同位素組成屬虧損型,在εNd(t)-(87Sr/86Sr)i相關(guān)圖上(圖7),投影在第二象限,位于OIB范圍內(nèi)。一件輝長(zhǎng)巖樣品的同位素組成表現(xiàn)為Nd略虧損,Sr富集的特征,在εNd(t)-(87Sr/86Sr)i相關(guān)圖上位于第一象限。另外兩件樣品表現(xiàn)了富集型地幔特征,在εNd(t)-(87Sr/86Sr)i相關(guān)圖上位于第四象限。
表7牛鼻子梁巖體各類巖石Nd-Sr-Pb同位素分析數(shù)據(jù)
Table 7Nd, Sr and Pb isotopes for rocks of the Niubiziliang intrusion
Sample巖性Rb(×10-6)Sr(×10-6)87Rb/86Sr87Sr/86Sr±2σ(87Sr/86Sr)iεSr(t)401-G5斜長(zhǎng)二輝橄欖巖6.83127.90.1546510.7042740.0000100.7035-8.55Ⅱ5-14淡色輝長(zhǎng)巖8.96321.50.0807160.7054560.0000110.705013.64Ⅱ5-15輝長(zhǎng)巖15.43501.80.0890380.7066860.0000120.706230.50Ⅱ6-5橄欖二輝角閃石巖9.72165.40.1701120.7063790.0000130.705520.22Sample巖性Sm(×10-6)Nd(×10-6)147Sm/144Nd143Nd/144Nd±2σ(143Nd/144Nd)iεNd(t)401-G5斜長(zhǎng)二輝橄欖巖1.114.460.15120.5127880.0000090.5124305.02Ⅱ5-14淡色輝長(zhǎng)巖1.917.940.14640.5125600.0000070.5122140.81Ⅱ5-15輝長(zhǎng)巖5.1323.540.13250.5124090.0000070.512095-1.52Ⅱ6-5橄欖二輝角閃石巖1.225.020.14770.5125210.0000080.512172-0.02Sample206Pb/204PbSE(%)207Pb/204PbSE(%)208Pb/204PbSE(%)(206Pb/204Pb)i(207Pb/204Pb)i(208Pb/204Pb)i401-G4-218.54570.000615.60020.000538.49710.001617.90615.56637.946401-G518.18590.000415.57310.000438.26590.001117.89815.55837.980Ⅱ5-1418.62190.000515.64810.000438.72670.001518.01615.61538.095Ⅱ5-1518.53560.000315.62200.000338.37810.001318.04115.59538.054Ⅱ6-518.92410.000715.63190.000639.00340.001817.82915.57338.204
圖7 εNd(t)-(87Sr/86Sr)i相關(guān)圖Fig.7 εNd(t) vs. inital 87Sr/86Sr of the intrusion
(206Pb/204Pb)i=17.829~18.041,(207Pb/204Pb)i=15.558~15.615,(208Pb/204Pb)i=37.980~38.204,在初始Pb同位素相關(guān)圖中,數(shù)據(jù)點(diǎn)都落在了地球等時(shí)線右側(cè),表明富含放射成因的鉛同位素(圖8)。在初始Pb同位素的相關(guān)圖中,這些數(shù)據(jù)點(diǎn)都位于虧損地幔與富集地幔EMⅡ之間。
利用橄欖石-熔體平衡原理可以估算原生巖漿的MgO含量。Mg-Fe在橄欖石-熔體之間的分配系數(shù)為一相對(duì)穩(wěn)定的值,即KdOl-Melt=(FeO/MgO)Ol/(FeO/MgO)magma=0.30±0.03,Kd隨壓力的增大而增大,一般低壓時(shí)取0.30,高壓時(shí)取0.33(Roeder and Emslie, 1970)。由于Fo值最高的橄欖石可能更接近于液相線橄欖石的組成,我們?nèi)⌒遍L(zhǎng)二輝橄欖巖中Fo為84的橄欖石作為液相線橄欖石的代表,該巖石中的FeO含量為12.27%,由此可以估算出與之處于平衡狀態(tài)的巖漿中MgO的含量:WMgO=0.56095KdFo/(1-Fo)WFeO(Kd=0.30),結(jié)果為10.8%,屬高鎂拉斑玄武質(zhì)巖漿范疇。
根據(jù)伍德-坂野二輝石地質(zhì)溫度計(jì)計(jì)算得到二輝橄欖巖和橄欖輝長(zhǎng)巖中二輝石共結(jié)溫度為1100~1178℃(Wood and Banno, 1973)。二輝石溫度計(jì)是經(jīng)常使用的經(jīng)典型地質(zhì)溫度計(jì),其結(jié)果合理。本文中獲取的二輝石平衡溫度應(yīng)該可以代表主體巖漿結(jié)晶溫度。
圖8 (207Pb/204Pb)i-(206Pb/204Pb)i和(208Pb/204Pb) i-(206Pb/204Pb)i相關(guān)圖(據(jù)Allegre et al., 1988; Zindler and Hart, 1986)Fig.8 Initial 207Pb/204Pb and 208Pb/204Pb versus initial 206Pb/204Pb of the intrusion (after Allegre et al., 1988; Zindler and Hart, 1986)
牛鼻子梁巖體中所有的超鎂鐵質(zhì)巖石和部分鎂鐵質(zhì)巖石具有正堆晶結(jié)構(gòu),此外還有輝長(zhǎng)結(jié)構(gòu)、反應(yīng)邊結(jié)構(gòu),似斑狀結(jié)構(gòu),嵌晶結(jié)構(gòu)和幾種包含結(jié)構(gòu)。充分反映了非平衡的分離結(jié)晶作用主導(dǎo)了巖漿房結(jié)晶的過程。由巖相學(xué)可知,在含橄欖石的各類巖相中,橄欖石是主要的堆晶相,其次是斜長(zhǎng)石,所以巖漿結(jié)晶的早期階段橄欖石是最主要的分離結(jié)晶相,其次為少量的斜長(zhǎng)石。在輝長(zhǎng)巖相中,堆晶相有單斜輝石也有斜長(zhǎng)石,所以隨著巖漿結(jié)晶過程的進(jìn)行,既有單斜輝石的分離結(jié)晶/堆晶,也有斜長(zhǎng)石的分離結(jié)晶/堆晶。
在Harker變異圖中,各主量元素含量與MgO具有明顯的相關(guān)性。在圖9中,超鎂鐵質(zhì)巖石主要位于Ol、Opx趨勢(shì)線方向演化,而鎂鐵質(zhì)巖石主要位于Cpx、Pl方向演化。從超基性巖到基性巖,Al2O3、CaO含量隨SiO2的升高而升高,說明了巖漿中發(fā)生了橄欖石的分離結(jié)晶或發(fā)生了斜長(zhǎng)石和單斜輝石的堆集;從基性巖到中酸性巖,Al2O3、CaO含量隨SiO2升高而降低,說明巖漿中的長(zhǎng)石逐漸由基性斜長(zhǎng)石演化到酸性斜長(zhǎng)石,與英云閃長(zhǎng)巖中主要為中長(zhǎng)石和更長(zhǎng)石這一事實(shí)是相吻合的。另外,樣品Ⅱ6-8除了中長(zhǎng)石和更長(zhǎng)石外還有少量的拉長(zhǎng)石,這應(yīng)該是造成該樣品正銪異常的原因。樣品Ⅱ6-8比樣品Ⅱ6-4的SiO2含量高,這與巖相中石英含量高(30%)是對(duì)應(yīng)的。因?yàn)槭⒅邢⊥猎乜偭康?小于1),所以導(dǎo)致樣品Ⅱ6-8稀土元素總量較低(∑REE=20.10)。
圖9 Harker變異圖Fig.9 Harker variation diagram of Niubiziliang intrusion
理論上,玄武質(zhì)巖漿分離結(jié)晶作用所產(chǎn)生的巖石系列的化學(xué)組分應(yīng)當(dāng)具有從鎂鐵質(zhì)到中性再到長(zhǎng)英質(zhì)的連續(xù)演化特征。然而,由于低壓下過渡組分的殘余巖漿的分離結(jié)晶作用是非常快的,所以鎂鐵質(zhì)端元和長(zhǎng)英質(zhì)端元之間的中間過渡成分并不常見,常常出現(xiàn)組分上的跳躍(即Daly間隔)(Yoder, 1973; Clagus, 1978; Peccerilloetal., 2003)。在Harker圖解中可以看到,鎂鐵質(zhì)-超鎂鐵質(zhì)巖石樣品與石英閃長(zhǎng)巖和英云閃長(zhǎng)巖數(shù)據(jù)點(diǎn)之間也存在一個(gè)不連續(xù)的間隔,即Daly間隔。
如前所述,牛鼻子梁巖體野外和鏡下多見圍巖捕虜體,這些現(xiàn)象直接說明了同化混染作用的存在。另外,一些地球化學(xué)證據(jù)也佐證了這一觀點(diǎn)。如果將沒有受到同化混染或受同化混染很弱的斜長(zhǎng)二輝橄欖巖(εNd(t)為+5.03、εSr(t)為-8.55)樣品來代表源區(qū)特征,那么源區(qū)表現(xiàn)為L(zhǎng)REE富集,Nb、Ta弱虧損等特征。牛鼻子梁巖體所有的超鎂鐵質(zhì)巖石(除角閃石巖)樣品均表現(xiàn)了LREE富集,Nb、Ta虧損或弱虧損的特征,說明該類巖石未遭受同化混染或同化混染較弱。而角閃石巖和鎂鐵質(zhì)巖石除具有LREE富集和明顯的Nb、Ta負(fù)異常外,還具有不同程度的P、Ti負(fù)異常;特別是石英閃長(zhǎng)巖和英云閃長(zhǎng)巖還具有Zr、Hf的正異常,這說明鎂鐵質(zhì)巖石均遭受了不同程度的同化混染作用,而閃長(zhǎng)巖類巖石同化混染程度最強(qiáng)(Taylor and Mclennan, 1985)。
由Nd、Sr、Pb同位素組成可以看出,樣品整體分布于虧損地幔與EMⅡ之間,也說明牛鼻子梁巖體遭受了同化混染作用。上地殼和下地殼的(La/Nb)PM和(Th/Ta)PM值有很大的區(qū)別,因此可以用來區(qū)分混染物質(zhì)的來源(Nealetal., 2002),圖10中所有數(shù)據(jù)點(diǎn)均位于平均上地殼范圍附近,說明了混染物主要是上地殼物質(zhì)。牛鼻子梁巖體中的捕擄體普遍來自于金水口巖群的黑云母片巖、石英巖、片麻巖、大理巖,這些巖石的原巖應(yīng)該是陸源碎屑巖和碳酸鹽巖,雖然經(jīng)歷了角閃巖相的區(qū)域變質(zhì)作用,但仍然保留了表殼巖系的Nd、Sr、Pb同位素和元素地球化學(xué)特征。
圖10 (Th/Ta)PM-(La/Nb)PM圖解估計(jì)地殼同化混染Fig.10 PM-normalized Th/Ta vs. La/Nb estimating crusal contamination
綜合前述的同化混染作用和分離結(jié)晶作用可知,Ⅰ區(qū)巖漿結(jié)晶時(shí),分離結(jié)晶/堆晶作用最強(qiáng),由大量的堆晶相組成(Mg#=0.80~0.83),Nd、Sr同位素組成屬虧損型,Nb/U值最大(平均為13.8),同化混染作用較弱;Ⅱ區(qū)巖漿結(jié)晶時(shí),分離結(jié)晶/堆晶作用較強(qiáng),大部分由堆晶相組成(Mg#=0.55~0.83),εNd(t)在零附近,Sr同位素表現(xiàn)為富集型,Nb/U值降低(平均為12.4),同化混染作用增強(qiáng);在Ⅲ區(qū)巖漿結(jié)晶時(shí),分離結(jié)晶/堆晶作用較弱,Nd、Sr同位素均表現(xiàn)為富集型,Nb/U值最小(平均為4.7),特別是到石英閃長(zhǎng)巖和英云閃長(zhǎng)巖結(jié)晶時(shí),分離結(jié)晶作用最弱,并出現(xiàn)Zr、Hf正異常,同化混染強(qiáng)度最大。這些證據(jù)說明,同化混染作用的強(qiáng)度伴隨著巖漿結(jié)晶過程而逐漸加大。大量的同化混染作用會(huì)促使巖漿由拉斑玄武質(zhì)系列轉(zhuǎn)化為鈣堿性系列,導(dǎo)致巖漿演化方向由Fenner趨勢(shì)(鐵富集)轉(zhuǎn)化為Bowen趨勢(shì)(硅堿富集)。
如前所述,牛鼻子梁巖體所有巖石樣品均表現(xiàn)出LREE富集型特征,包括Nd、Sr同位素虧損的樣品也是如此,所以很可能是源區(qū)使然。虧損型地幔源區(qū)可能經(jīng)歷過一次地幔交代作用,使得LREE富集,而交代作用的時(shí)間與巖漿形成的時(shí)間間隔較短,同位素還沒有達(dá)到均一化,所以Sr還是虧損的。另外,牛鼻子梁巖體中主要形成于巖漿結(jié)晶早期階段的橄欖巖相均含有褐色普通角閃石,且數(shù)量最多可達(dá)15%。此外,還有相當(dāng)數(shù)量的橄欖二輝角閃石巖,其中的角閃石含量為60%~75%,這些現(xiàn)象充分反映了巖漿富水,說明原始巖漿是富水的巖漿,這也可以用地幔交代作用來解釋。同時(shí)因?yàn)楦凰?,降低了液相線溫度,正常溫度下(1178℃)部分熔融程度增加,導(dǎo)致原生巖漿MgO含量(10.8%)較高。
根據(jù)李榮社等(2011)研究,在早古生代晚期階段,祁漫塔格、祁連等洋盆相繼閉合,從而導(dǎo)致在泥盆紀(jì)期間昆侖山及其以北的柴達(dá)木地塊、祁連褶皺帶、阿拉善地塊連為一體,并整體抬升為陸。根據(jù)張雪亭等人(2007)的研究,晚泥盆世-石炭紀(jì)中期古亞洲洋南向消減,引發(fā)現(xiàn)今塔里木-華北或西域-中朝(北中國(guó)板塊)與現(xiàn)北羌塘-揚(yáng)子等陸塊(南中國(guó)板塊)間分裂。綜上所述,盡管柴達(dá)木地塊北緣在泥盆紀(jì)期間的構(gòu)造格局尚不十分明瞭,但處于總體穩(wěn)定、邊緣拉張裂解環(huán)境應(yīng)該還是比較可信的。世界上大多數(shù)堆晶結(jié)構(gòu)、堆晶層理特別發(fā)育的層狀巖體都生成于克拉通區(qū)的拉張裂解環(huán)境,也可以視為對(duì)牛鼻子梁巖體構(gòu)造環(huán)境的佐證。
從全球范圍來看,含鎳銅鉑礦的巖體可以在多種構(gòu)造環(huán)境中產(chǎn)出,但最有利的構(gòu)造背景主要有四種類型,克拉通內(nèi)部和邊緣裂谷或伸展環(huán)境即為其中一類。牛鼻子梁巖體位于柴達(dá)木地塊邊緣,巖體形成時(shí)的構(gòu)造環(huán)境屬于拉張裂解環(huán)境,可以將其歸為大陸邊緣裂解環(huán)境,是形成鎳銅鉑硫化物礦床的有利構(gòu)造背景。
根據(jù)現(xiàn)有資料,含鎳銅鉑礦巖體(及火山巖)的原生巖漿均為高鎂拉斑玄武巖、苦橄巖和科馬提巖,換句話說也就是MgO含量要大于10%。牛鼻子梁巖體的原生巖漿的MgO含量為10.8%,位于該范圍內(nèi)。
世界上大多數(shù)賦含鎳銅鉑硫化物礦床的巖體都屬層狀巖體,例如Bushveld、Great Dyke、Stillwater、坡一、坡十等。所以層狀巖體是形成鎳銅鉑硫化物礦床的主要巖體類型。牛鼻子梁巖體即為該類巖體。
對(duì)于所有的巖漿礦床而言,巖漿分異程度都是至關(guān)重要的成礦因素。這是因?yàn)榉蛛x結(jié)晶是幔源巖漿演化的主要機(jī)制,橄欖石、輝石、鐵鈦氧化物等富含F(xiàn)e2+礦物分離結(jié)晶會(huì)顯著降低巖漿中Fe2+的活度,從而降低達(dá)到硫化物飽和點(diǎn)的硫溶解度(SCSS),并增加演化巖漿中硫的豐度,斜長(zhǎng)石的大量分離結(jié)晶也會(huì)增加演化巖漿中硫的豐度,這些效應(yīng)累計(jì)到一定程度,就會(huì)使巖漿中的硫化物達(dá)到過飽和并熔離(Naldrett, 2009; Lightfoot and Hawkesworth, 1997; Irvine, 1975)。牛鼻子梁巖體巖石類型豐富,從斜長(zhǎng)二輝橄欖巖到英云閃長(zhǎng)巖均有出現(xiàn),且分離結(jié)晶在巖漿演化過程中占主導(dǎo)地位,說明巖漿分異充分,有利于成礦物質(zhì)的富集。
富水的巖漿在生成時(shí)往往部分熔融程度較高,有利于更多的硫化物進(jìn)入巖漿。巖漿富水有利于成礦物質(zhì)的運(yùn)移與聚集,是成礦過程的重要媒介。所以巖漿含水量是評(píng)價(jià)巖體含礦性的重要指標(biāo)。巖漿富水,會(huì)促使含水礦物在巖漿結(jié)晶的較早階段就開始大量結(jié)晶。牛鼻子梁巖體下部和中部層序的橄欖巖相、輝石巖相和輝長(zhǎng)巖相普遍含有較多的褐色普通角閃石;在上部層序中含有較多的角閃石巖。這些現(xiàn)象說明,由于形成牛鼻子梁巖體的巖漿普遍富水,在巖漿結(jié)晶的較早階段,就開始結(jié)晶出實(shí)質(zhì)性數(shù)量的角閃石;而且,在巖漿演化的較晚階段,由于巖漿含水量進(jìn)一步增大,結(jié)晶出大量角閃石,形成角閃石巖。這種現(xiàn)象在同類巖體中是不多見的。
牛鼻子梁巖體的野外地質(zhì)觀察、巖相學(xué)與巖石地球化學(xué)都證明巖漿經(jīng)歷了較強(qiáng)的同化混染作用。地殼混染作用會(huì)導(dǎo)致巖漿中SiO2濃度的增加、溫度的降低以及氧逸度的升高,這些都會(huì)降低巖漿中硫化物達(dá)到飽和點(diǎn)的硫溶解度(SCSS);另外,如果有外來S的加入還會(huì)顯著增加巖漿中S的豐度,從而促使硫化物達(dá)到過飽和并成礦。
橄欖巖相、橄欖二輝巖、橄欖輝長(zhǎng)巖和橄欖二輝角閃石巖中橄欖石的NiO含量分別是0.06%~0.17%、0.09%~0.11%、0.13%~0.23%、0.15%~0.18%。相應(yīng)的平均值分別是0.12%、0.10%、0.17%、0.16%。橄欖石中Ni豐度變化于448×10-6~1935×10-6。Naldrett(1999)認(rèn)為未分異的飽和硫化物的巖漿中橄欖石正常Ni含量為2500×10-6,此值意味著該巖體不易成礦。只有當(dāng)橄欖石中Ni虧損到2200×10-6以下時(shí),才顯示出該巖體發(fā)生過不同程度的硫化物熔離。一般而言,橄欖石中Ni含量越低越有利于成礦。牛鼻子梁巖體各種巖相中橄欖石的Ni含量均低于2200×10-6,表明巖漿中曾發(fā)生過硫化物熔離。但在各種巖相中硫化物熔離的程度是不相同的。橄欖巖相和橄欖輝石巖中橄欖石的Ni含量明顯低于橄欖輝長(zhǎng)巖和橄欖二輝角閃石巖中的相應(yīng)值,表明形成前兩類巖石的巖漿經(jīng)歷了比較充分的硫化物熔離作用,有利于成礦。在圖11上,Ⅰ區(qū)的樣品(主要是橄欖巖和橄欖輝石巖)均位于2線和3線之間,而Ⅱ區(qū)和Ⅲ區(qū)的樣品(主要是橄欖輝長(zhǎng)巖和橄欖二輝角閃石巖)主要位于1線和2線之間,進(jìn)一步證明了上述認(rèn)識(shí)。
圖11 牛鼻子梁巖體中橄欖石鎳含量與鎂橄欖石分子含量(Fo)的關(guān)系(分區(qū)據(jù)Simpkin et al., 1970;秦克章等, 2007)Fig.11 Relation between the Ni content of olivine and the forsterite content (Fo) of Niubiziliang intrusion (after Simpkin and Simth, 1970; Qin et al., 2007)
(1)牛鼻子梁巖體中輝長(zhǎng)巖的鋯石U-Pb年齡為367.0±2.0Ma,形成于晚泥盆世。
(2)巖石類型包括斜長(zhǎng)二輝橄欖巖、斜長(zhǎng)單輝橄欖巖、角閃二輝橄欖巖、角閃橄欖巖、橄欖二輝巖、角閃二輝巖、橄欖二輝角閃石巖、角閃橄欖輝長(zhǎng)巖、細(xì)粒輝長(zhǎng)巖、似斑狀輝長(zhǎng)巖、暗色輝長(zhǎng)巖、輝長(zhǎng)巖、淡色輝長(zhǎng)巖、石英閃長(zhǎng)巖和英云閃長(zhǎng)巖。巖漿分異充分,巖石類型豐富。巖體層狀和紋層狀構(gòu)造發(fā)育,堆晶層理清晰,垂向分帶明顯,屬層狀雜巖體。
(3)巖漿演化過程中主要發(fā)生了橄欖石的分離結(jié)晶作用,此外還有少量的斜長(zhǎng)石分離結(jié)晶/堆晶作用。
(4)巖體與圍巖之間發(fā)生了較強(qiáng)的的同化混染作用,混染物主要是金水口巖群。同化混染強(qiáng)度伴隨著巖漿演化過程而逐漸增大。
(5)巖體形成的構(gòu)造環(huán)境為大陸邊緣裂解環(huán)境。虧損型地幔源區(qū)經(jīng)過地幔交代作用,部分熔融形成高鎂拉斑玄武質(zhì)巖漿(MgO=10.8%),主體巖漿結(jié)晶溫度為1100~1178℃。
(6)牛鼻子梁巖體具有適合形成鎳銅硫化物礦床的構(gòu)造環(huán)境、巖體類型、原始巖漿、巖漿含水量、巖漿分異、同化混染程度和橄欖石鎳含量,具有很大的成礦潛力。
致謝在論文修改過程中,得到了李楚思教授細(xì)致耐心的指導(dǎo);匿名審稿人對(duì)本文進(jìn)行了認(rèn)真的審閱,提出了寶貴的修改意見,使我們獲益良多;在此一并深致謝意。
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