• <tr id="yyy80"></tr>
  • <sup id="yyy80"></sup>
  • <tfoot id="yyy80"><noscript id="yyy80"></noscript></tfoot>
  • 99热精品在线国产_美女午夜性视频免费_国产精品国产高清国产av_av欧美777_自拍偷自拍亚洲精品老妇_亚洲熟女精品中文字幕_www日本黄色视频网_国产精品野战在线观看 ?

    Global Gold Mining: Is Technological Learning Overcoming the Declining in Ore grades?

    2013-06-15 17:32:40AdrianaDomnguezAliciaValero

    Adriana Domínguez, Alicia Valero

    1CIRCE, Centre of Research for Energy Resources and Consumptions, Universidad de Zaragoza, Zaragoza, Spain

    Global Gold Mining: Is Technological Learning Overcoming the Declining in Ore grades?

    Adriana Domínguez1?, Alicia Valero1

    1CIRCE, Centre of Research for Energy Resources and Consumptions, Universidad de Zaragoza, Zaragoza, Spain

    Submission Info

    Communicated by Sergio Ulgiati

    Gold mining

    Technological learning

    Declining ore grades

    Learning curves

    Future availability of mineral resources is influenced by two opposed facts. On the one hand, general trends suggest a long-term decline in ore grade, which increases energy consumption in mining industry. But on the other hand there have been technological transitions that might avert rises in energy consumption. The aim of this paper is to become acquainted if technological breakthroughs that have occurred can preclude the rising energy demand for the gold mining industry. As experience is acquired, material and energy efficiency increase and technical changes can be expressed through the so called learning curves. Accordingly, the learning curve approach is applied to several data sets of 17 major gold producing countries. Our results show that technological learning is as dependent on ore grade as it is on mining operation and recovery processes. Applying the learning curve method we obtain average progress ratios varying from +20% to -22%. This survey allows us to have a better understanding of the mining sector and the outcomes of technology evolution together with ore grade declining by means of identifying best mining practices around the world.

    ? 2013 L&H Scientific Publishing, LLC. All rights reserved.

    1 Introduction

    The mining industry is experiencing groundbreaking changes such as commodity price fluctuating, rising energy demand, water and cyanide consumption, increasing costs, declining ore grades, greenhouse gas emissions, increasing waste volumes and the challenge to achieve a more sustainable industry. Thence, sustainability practices have become important for most major mining companies in order to reach a balance between socio-political, economic and environmental issues.

    Otherwise, there is a debate about the availability of commodities in the future. Although there is evi-dence supporting the long-term decline in gold ore grades, there also exists the possibility that technological learning will overwhelm this fact. Hence, this paper analyzes the relationship between two issues: the decline in ore grades and the rising in energy consumption per ton of metal extracted.

    The analysis of data set on historic gold mining in the main gold producing countries was carried out by means of linking resource extraction with energy use through the learning curves approach. Learning curves were originally developed to evaluate the effect of learning by doing in manufacturing. However, there are new applications such as analysis innovation and technical change in energy technology.

    This paper looks over energy data on gold mining for Australia, North America, Africa and the Asia-Pacific compiled by Mudd [2-3], who pointed out the critical aspects of mineral resource sustainability such as resource intensity linked to technology.

    1.1 Gold mining issues

    1.1.1 Production and reserves

    The world gold production during 2010 was produced in the following countries: China (13.8%), Australia (10.2%), USA (9.2%), South Africa (7.6%), Russia (7.6%), Peru (6.8%), Indonesia (4.8%), Ghana (4%), Canada (3.6%), Uzbekistan (3.6%), Brazil (2.6%), Papua New Guinea (2.4%), Mexico (2.4%), Chile (1.6%) and other countries (19.7%). The major reserves are located in Australia (14.4%), South Africa (11.84%), Russia (9.86%) and Chile (6.71%). Reserves data are dynamic because they may be reduced as ores are mined and/or the extraction feasibility decreases. More commonly, they may continue to increase as further deposits (known or recently discovered) are developed. Additionally, currently exploited deposits that are more completely explored and/or new technology or economic variables that may appear enhance their economic feasibility [4]. Hence, reserves data are a major issue because they betray where the largest resources are, allowing us to be aware of the countries that must improve its mining methods in order to extract resources in the best possible way.

    1.1.2 Energy consumption

    Gold production is one of the processes with the greatest energy requirements in the mining industry. Energy consumption is dependent on several factors such as the recovery process and the kinds of mining operations analysed in this paper. For instance, energy consumed in open pit (OP) mining usually is greater than the energy required in underground (UG) mining because ore grades in open pit mines are smaller than those presented in underground mines. For open pit mines the average energy requirement is 170,000 GJ/t whilst for underground mining is 127,000 GJ/t of gold produced. The energy required to separate the gold from the mine increases abruptly when the concentration of the ore in a deposit tends to zero.

    1.2 Learning curves theory

    Learning curves come out as an empirical method to assess the effect of learning on technical change. As experience is acquired, efficiency and quality upgrade, mining costs decline and wastes are reduced. Technical change is a gradual process that entails technical knowledge and investment, but also an increase in material and energy efficiency. Both material and energy efficiency increase independently and changes can be leaded to the learning by doing concept [5]. Technical change is introduced by implementing technology learning rates, which specify the quantitative relationship between the cumulative experiences of the technology and cost reductions [6].

    There is a widespread use of learning curves because of their usefulness to quantify the impact of increased experience and learning of a given technology. This allows obtaining a representation of technical change with a variety of different indicators of technological performance.

    A good number of studies based on the learning curves theory have been carried out. For instance, Soderholm [6] used learning curves for assessing the economic outlook of renewable energy technologies to link future cost developments to current investment in new technology. Other studies [7,8] about the impact of quality on learning, suggest that learning is the link between quality improvement and productivity increase.

    The simplest and most frequently representation of learning curves in energy technology studies is the Wright’s log-linear model [9]:

    whereYxrepresents the energy required to produce thex-th unit,Y0is the theoretical energy of the first production unit,xis the sequential number of the unit for which the energy is to be computed andbis a constant reflecting the rate energy decrease from year to year (learning index) and is calculated as:

    whereSis the energy slope expressed as a decimal value (learning rate), while (1-S) is defined as the progress ratio (PR) which expresses the fraction to which energy requirements are reduced with cumulated production.

    Nonetheless, there is a limit on the energy use to ore production that cannot be exceeded with increasing experience and in this case it is the minimum theoretical energy required to concentrate a substance from an ideal mixture of components [10] and is given by the following expression:

    wherexiis the concentration of substancei, Ris the gas constant (8.3145 J/molK) andT0is the reference temperature (298.15 K).

    Considering the energy limiting value, the learning curve can be expressed as:

    Equation (4) integrates thermodynamic concepts to the learning curve analysis.

    In this case technology learning rates state the correspondence between the cumulative experience of the technology and the energy requirement reductions.

    Energy requirement reductions are the result of learning by doing. For instance, performance improves as new technologies and mining methods are implemented. Accordingly, learning curves will be used to empirically quantify the impact of accomplishing new mining practices on the energy consumptions of ore mining.

    There is an enhancement for the simplest learning curve by applying a factor related with research and development. This extended formulation is known as the two factor learning curve (TFLC) expressed as follows:

    whereKSis the knowledge stock and c is the elasticity of learning by researching [11]. Both types of learning curves are the most commonly used to assess technology learning rates in the energy sector [6].Multiple-factor learning curves that account for other independent variables besides cumulative production represent an approach to get a better understanding of technological learning by enhancing the knowledge base [12,13].

    Learning rates depend on the data points that are chosen. Previous surveys reveal significant variability in estimated rates between different energy technologies, which ranges from 1% to 41.5% [11]. On the other hand, the study developed by McDonald shows that the average value of learning rates for energy technologies is 16-17% and learning rates for manufacturing is 19-20% [14]. Negative learning rates can be interpreted as a consequence of experience depreciation, if no important external factors (such as declining ore grades in mining technologies) are influencing the production process.

    The estimation of learning curves has some highlights. For instance, the need to explore the effect of detaching single observations especially outliers that may affect the learning rate estimate.

    2 Learning curves applied to global gold mining

    Learning rates and progress ratios were calculated for each mine using Eq. (2) and Eq. (4). The information was grouped according to the different mining technologies used, because learning by doing will differ between mines, countries and technologies.

    Progress ratios are different for each country and even for each mine although they use the same recovery process technology. This is due to inherent factors to each mine such as project age, depth, ore types, etc. Results of the analysis performed for different mining operations and recovery processes are shown in Table 1.

    The assorted configurations of gold mines like open pit (OP), underground (UG) or mixed (MIX), as well as the energy source (diesel, coal, hydro, gas or any mix among them) are factors that influenced the progress ratio.

    Recovery process technologies show average progress ratios around ±25% as shown in Figure 1. Open pit operations with heap leach technology (HL) as recovery process as well as underground operations using carbon in pulp (CIP) 1 technology are the mining options with the greatest progress ratios.

    2.1 Argentina

    Gold is produced in two open pit mines; Veladero and Cerro Vanguardia. There is another important mine in Argentina named Bajo la Alumbrera in which gold and copper are produced.

    The Veladero mine [16] with typical ore grades under 2.5 g/t Au started its production on 2005 so it is a new mine that has been increasing its production with lower energy requirements. Hence positive learning rates are obtained when applying the learning curve approach. Otherwise, Cerro Vanguardia mine with ore grades between 7 and 8 g/t Au has been dispalying a decline in its ore grade. Although cumulative production has grown, the energy per unit of gold produced has also increased and thereby negative progress ratios are presented. Available data: from 2005 through 2007.

    Negative progress ratios convey that technological learning has been unable to overcome the increase in energy consumption during mining operations due to the declining in ore grade. On the other side, positive progress ratios imply that mining recovery processes have achieved to maintain or decrease the energy consumption during mining operations through time. Consequently, the progress ratio becomes an indicator to identify those mines where mining practices are successful when saving energy.

    Fig. 1 Distribution of average progress ratios for gold mining industry.

    Table 1 Progress ratio for global gold mining

    In the coming sections, the key aspects of gold mining in the largest gold producer countries are briefly analyzed.

    2.2 Australia

    Gold is produced in almost 30 mines, including open pit, underground and mixed. A previous work accomplished by Valero et. al. [17] analyzed the influence of technical development and declining ore grades on the availability of Australian gold resources. The obtained results suggest that although progress in technology has been made, in most cases energy requirements are increasing, because the main variable is the ore grade. Progress ratios represent the amount of improvement in mining technologies for several mines in Australia, such as Kidston [18], Henty [19], Kalgoorlie [20], Agnew [21], St Ives [22], Plutonic [23], Darlot [15], Lawers [15], Superpit [23], Mt. Leyshon [24], Tanami [25], Boddington [23], Pajingo [26], Sunrise Dam [27], Challenger [23], Ravenswood [28], Peak [29]. Available data: from 1990 through 2008.

    2.3 Brazil

    There are two mines in which gold is extracted with an ore grade range less than 0.35 g/t Au, Maricunga and Paracatu [30]. Maricunga mills only 35% of the total ore milled in Paracatu. In that case, the energy consumption in mining is related with quantity (cumulative production) and quality (ore grade) resulting a positive PR of 24% for Maricunga but not for Paracatu, which has a negative PR. Amapari mine [31] shows an improvement from 2005 to 2006 when it reduces its energy requirement almost 60% even though ore grade decreases. Hence, it presents the highest progress ratio of all mines analyzed. Available data: from 2001 through 2007.

    2.4 Canada

    Dome-Porcupine mine belongs to Goldcorp Company [32], this mine does not show variation in progress ratios although three situations were identified: 1) with the same ore grade in 1997 and 2005, an increment in energy consumption was presented, this can imply that there was no improvement in the process and that this increase can be caused by the deterioration in the mining equipment, 2) energy consumption can diminish although ore grade declines; for instance from 1997 to 1998, where energy reduction was influenced by the increase in the tons of ore milled, leading to a positive learning rate, and 3) the expected behavior of energy increase when ore grades decrease and vice verse.

    Hemlo [15], Musselwhite [32] and Campbell [23] mines show negative progress ratios as a result of ore grade declining, as well as the increment in energy consumption although ore grade remains constant.

    Eskay Creek Mine belongs to Barrick’s Company. This mine is a clear example of ore grade decliningtrend insomuch as ore grade in 2001 was 53.14 g/t Au and then in 2007 it was of 20.91 g/t Au. This situation has an effect on the energy consumption because in 2001 the energy required was 35.09 MJ/kg Au while in 2007 it reached 203.378 MJ/kg Au. Accordingly, negative progress ratios are presented. For values of ore grade between 40 and 90 g/t Au, besides Eskay Creek, there is another mine Red Lake from Goldcorp. Inc. [32]. Available data: from 1997 through 2007.

    2.5 Chile

    Coipa mine [33] uses conventional open pit mining methods and crushing, grinding and leaching operations to process gold. Energy consumption has been increasing over time, leading to negative progress ratios. Available data: from 2003 through 2004.

    2.6 Ghana

    The main gold producing country in West Africa is Ghana. For ore grades below 1.5 g/t Au, there are two mines from Gold Fields Co.: Tarkwa Gold Mine [34] and Damang Gold Mine [34]. The first one consists of six open pits, two heap leach facilities, and a CIL plant. The operation is currently mining multiplereef horizons from open pits and there is potential for underground mining in the future. Tarkwa has mineral resources equal to 433.75 gold tons and a mineral reserve of 280.6 tons. The second one is composed of multiple open pits, surface stockpile sources and a CIL plant, with a mineral resource of 133.2 gold tons and a mineral reserve of 59.5 tons.

    In accordance with the above information, it is reasonable that Damang mine has energy consumptions greater than Tarkwa mine for the same ore grade, leading to lower PR values. Furthermore, both mines show an increasing energy consumption trend under two conditions, when ore grades decrease and when cumulative production increase. Consequently, both mines have negative progress ratios, because under any circumstances there is an increase in energy consumption.

    AngloGold Ashanti has two mines in Ghana: Iduapriem [27] and Obuasi [23]. The decrease in ore grade together with the rising energy consumption, result in negative progress ratios for both.

    Available data: from 2004 through 2008.

    2.7 Guinea

    Siguiri gold mine belongs to AngloGold Ashanti Co. [23]. The annual production is 7.9 gold tons. It has a mineral resource of 138.9 gold tons and a mineral reserve of 73.7 tons. This mine fulfills the learning curve theory, since energy consumption decreases as cumulative production increases despite the ore grade is declining. Consequently, positive progress ratios are presented. Available data: from 2005 through 2007.

    2.8 Indonesia

    Kelian Equatorial Mining [35] is 90% owned by Rio Tinto. This open pit mine started its production in 1992 and finished it in 2004. The gold recovery process uses SAG and Ball Mills followed by gravity separation and carbon in leach (CIL) cyanidation. This mine shows a neutral PR. Available data: from 2002 through 2004.

    2.9 Laos

    MMG owns Seapon mine [36] which has gold and copper operations. Gold has been produced since 2002. In early 2005, an expansion of the original gold processing facility was completed doubling the capacity of the gold processing plant to 2.5Mt/year, with a new crusher and mill allowing more flexibility and efficiency in the treatment of Sepon ore. The mine has 93.5 tons of gold resources and a reserve of 5.1 tons. The Seapon gold mine is expected to be operational until 2012. There is not enough data to establish a trend in its energy consumption (its PR is zero). Available data: 2003 and 2005.

    2.10 Mali

    Sadiola Gold Mine [37] is operated by AngloGold Ashanti. Yatela Gold Mine performs the elution and smelting processes at the nearby Sadiola Gold mine. Morila Gold Mine [38] is a joint venture company between Randgold (40%), AngloGold Ashanti Ltd (40%) and the State of Mali (20%). During the first quarter of 2009, a successful transition was made from open pit mining to stockpile treatment. The operation is expected to come to an end in 2013 although the mine is currently investigating the opportunity to retreat the Tailings Storage Facility (TSF) material, which would extend the mine life by approximately five years. For ore grades under 3 g/t Au, energy consumption increases as cumulative production rises, leading to negative progress ratios. The positive progress ratio is due to the increment in ore grade. For the ore grades ranging between 3 and 6 g/t Au, energy consumptions vary for each mine. However, the general trend is a decreasing in energy consumption when cumulative production grows. Consequently, a null progress ratio is presented. Available data: from 2005 through 2007.

    2.11 Mexico

    San Dimas Mine [39] consists of five ore zones or blocks where underground gold and silver mining operations are carried out using mechanized cut-and-fill mining methods, with LHD equipment feeding either truck or rail haul to the mills. After milling, cyanidation, zinc precipitation and smelting, dore bars are poured and then transported to refineries in the United States. Over the last ten years investments have been made to significantly upgraded tailings management, increasing production and achieving a lower cost structure in the future. Besides, in 2005, crushing capacity was increased, as well as improvements to the chemical treatment and leaching area. Energy consumption increases although cumulative production grows and ore grade increases, but there is a change in 2005 where a reduction in energy requirements is presented despite the fact that ore grade decreases due to the improvement in the processes indicated above. Nevertheless, a negative progress ratio is presented. Available data: from 2004 through 2006.

    2.12 Namibia

    Navachab gold mine [40] recovers 85% of gold. After CIP extraction, elution and smelting, the unrefined bullion is sent to Switzerland, where it is refined. Energy consumption increases throughout the due to the decline in ore grades, leading to a negative progress ratio. Available data: from 2005 through 2007.

    2.13 Peru

    Pierina [15] is an open-pit mine, with truck and loader operations. Ore is crushed and transported through an overland conveyor to the leach pad area. Run-of-mine ore is trucked directly to a classic valley-fill type of leach pad. Pierina is currently engaged in energy efficiency optimization efforts which lead to decreasing energy consumptions or increasing energy efficiencies as well as reducing greenhouse gas emissions [41]. Over the last decade, improvements in the leach pad system as well as in the surface water management system have been made [42]. Despite the improvements made in the mine, energy consumptions continue growing due to the ore grade declining, leading to negative progress ratios. This can imply that technological efforts adopted by the mine aren’t enough to bring down the energy increasing trend.

    Yanacocha Gold Mine is the largest and most profitable gold mine in Latin America, with relatively low energy consumptions. It operates a complex of six open pit gold mines, five leach pads and two processing facilities. Gold is extracted from ore through a cyanide heap leach process. The solution is treated then by the Merrill Crowe process. After recovery, the contained metal is smelted and casted as bars containing 75% gold and 20% silver [23].

    Lagunas Norte mine is owned by Barrick Co. [33]. In 2006 began the development of a high grade area with a longer hauling cycle. Gold and silver are recovered in a conventional clarification and zinc precipitation circuit, using the Merrill- Crowe process. For this reason, a decrement in energy consumption from 2006 is observed, leading to a positive progress ratio, regardless the ore grade declining.

    Available data: from 2001 through 2007.

    2.14 Papua New Guinea

    Misima gold/silver mine [23] ended its operation in 2001 with stockpile milling anticipated to continue into 2004. Gold recovery used a standard crushing, grinding and carbon-in-pulp (CIP) flowsheet. All data analyzed for this mine indicates that both cumulative production and energy consumption increase. Besides, ore grades are declining, resulting in negative progress ratios.

    For ore grades varying between 3 and 5 g/t Au, there are two mines that are mined: Porgera and Lihir mines. Almost all data for this range is from Porgera mine.The energy consumption grows as cumulative production does, whilst progress ratios vary according to the ore grade changes. For the interval within 5 and 6 g/t Au of ore grade, Porgera mine reveals a slightly trend of ore grade decrease, whilst cumulative production increase. The result is a decreasing tendency of energy consumption prompting a positive progress ratio.

    The Porgera gold mine [23] is operated by a Barrick subsidiary. Both open-pit and underground mining methods are employed because it was initially an underground operation until 1997, but was resumed in 2002. Additionally an open-pit mining became increasingly important from 1993. A lot of changes have been made into the mining processes. For instance, the open pit has been mined in five stages, with final-stage overburden removal taking place during 2001. The open-pit truck and shovel fleet was expanded in 1995 and 1997. Besides, in 1999 a flotation expansion was installed as well as additional oxygen capacity to increase autoclave throughput. Run-of-mine ore is crushed and ground, gold is then recovered in a gravity circuit and flotation is used to recover a sulphide concentrate before the applying of CIP cyanide leaching process. The final step is the electrowinning process that produces bars of 88% gold average.

    The Lihir gold mine [33] is an open-pit mine consisting of two adjacent overlapping pits. Its operations include; crusher, SAG and ball mill circuit, flotation circuit, pressure oxidation and CIL processing facilities, and electrowinning and smelting facilities to produce gold doré.

    Available data: from 1997 through 2007.

    2.15 South Africa

    In South Africa the data are from the following mines: Harmony Group, Vaal River, Beatrix, Driefontein, South Deep, Kloof and West Field. Gold Fields company owns Beatrix, Driefontein, South Deep and Kloof.

    Beatrix Gold Mine [34] consists of four surface operating shafts that mine various gold bearing reefs from open ground and pillars. The ore is processed at two metallurgical plants, where milling, CIL process, elution and gravity circuits, electrowinning and smelting operations are carried out.

    Driefontein Gold Mine [34] includes eight shaft systems that mine various gold bearing reefs from open ground and pillars. Ore extracted from the bearing reefs is processed at three metallurgical plants. It has a centralized elution and carbon treatment facility since 2001. The mineral processing technology was based on SAG milling circuit followed by a cyanide leaching until the year 2003, when these processes were replaced by the CIP plant.

    Kloof Gold Mine [34] is composed of five shaft systems and two gold plants, the gold is produced from a combination of underground mining and processing of surface waste rock dump material. For the mineral processing, two operational metallurgical facilities are used, including a central elution and smelting facility. In 2001 and ACC Pump Cell CIP circuit was installed to replace the less efficient drum filtration and zinc precipitation. Additionally, the upgrade included the installation of continuous electrowinning sludge reactors.

    South Deep Gold Mine [34] incorporates two shaft systems that mine various auriferous conglomerates from open ground and pillars. The ore is processed at a central metallurgical plant. The mineral processing includes a milling circuit SAG, a CIP circuit, an elution system to finally recover gold by electrowinning and smelting processes.

    Great Noligwa underground gold mine [23] is situated close to the Vaal River. It comprises four gold plants, one uranium plant and a sulphuric acid plant. Great Noligwa has its own milling and treatment plant which applies conventional crushing, screening, grinding and CIL processes to threat the ore and extract the gold.

    Harmony Group in South Africa include the following mines: Bambanani, Doornkop, Kusasalethu, Evander, Joel, Kalgold, Masimong, Phakisa, Phoenix, Target, Tshepong and Virginia [43]. Sometimes the value of ore milled is too large compared with the values of other mines in the same ore grade scope. Therefore, it is probably that these data are referred to several mines. West Wits Operations include Driefontein, Kloof and South Deep Gold Mines [34].

    Harmony Group reports the highest energy consumption value, leading to a negative progress ratio. For ore grades from 6 to 7 g/t Au, the only existing mine is Kloof, which shows an increase in the energy consumption for the same ore grade value from 2004 to 2008, therefore a negative progress ratio is shown. Data in the span between 8 and 9 g/t Au is from West Wits Field, eventhoug ore grade decreased, energy consumption decreased too, leading to a null positive progress ratio. Available data: from 2003 through 2008.

    2.16 Tanzania

    North Mara gold mine consists of three open pit deposits and belongs to Placer Dome Company. AngloGold Ashanti Ltd owns Geita gold mine, which began production in 2000. Geita [27] is a multiple open-pit operation with underground potential. For ore grades between 3 and 5 g/t Au, most of the data isfrom North Mara, during 2003 and 2004 the ore grade is the same but the energy consumption differs greatly, almost by a 50%. The same situation is repeated for years 2005 and 2007 and despite of these observations, there is a declining trend in energy consumption, resulting in a positive progress ratio of 12%.

    Tulawaka Gold mine [33] consists of a completed open pit mine with an underground access ramp, an ore stockpile area and crushing plant and processing plant. The ore processing method includes SAG, gravity recovery and CIL. It is the only mine which report data in the span of 9 and 14 g/t Au. Within this large ore grade range the energy consumption falls as cumulative production increase, leading to a positive progress ratio of 11%.

    Bulyanhulu Mine [44] is owned by Barrick Gold Corp. Bulyanhulu is an underground trackless operation using long hole and drift and fill as its principal toping methods. It shows a clear downtrend in ore grade that results in an energy consumption increase as cumulative production rises. However, due to the fact that ore grade vary from one year to another without a clear trend of increase or decrease and this variation is not significant, the progress ratio is positive.

    Available data: from 2001 through 2007.

    2.17 United States

    Barrick Company [15] in USA owns several mines. Bald Mountain mine is an open pit, run-of mine with conventional heap leaching technology and carbon absorption for ore treatment.

    Cortez mine is mined by conventional open-pit methods. It employs three different metallurgical processes to recover gold. Lower-grade oxide ore is heap leached, while higher grade ore is treated in a conventional mill using cyanidation and a CIL process. Heap leached ore is hauled directly to leach pads for gold recovery.

    Golden Sunlight mine is mined by conventional open-pit methods. The ore treatment plant uses conventional CIP technology as well as San Tailing Retreatment (SRT). Goldstrike complex includes an open pit mine and two underground mines. The open pit is a truck and shovel operation using large electric shovels. While one of the underground mines is a high grade ore body which is mined by transverse longhole stoping, underhand drift and fill mining methods, the other is a trackless operation, using two different underground mining methods: long-hole open stoping and drift and fill. The mine consists of two processing facilities that are used for both the surface and underground operations: (i) an autoclave circuit and (ii) the roaster.

    Marigold mine is an open-pit operation that uses heap-leaching to process its ore.

    Round Mountain mine is a conventional open-pit operation that uses multiple processing methods including crushed ore leaching, run of mine ore leaching, milling of higher ore grade and the gravity concentration circuit.

    Turquoise Ridge mine uses underhand cut and fill mining methods. The ore is transported to an external mill for processing. The refractory gold ore is treated by pressure oxidation technology and gold is recovered using conventional CIL technology.

    Cripple Creek Victor JV gold mine [23] is a low-grade, open pit operation. The ore is treated using a valley-type, heap leach process with activated carbon used to recover the gold. The resulting doré buttons are shipped to a refinery for final processing.

    Fort Knox mine [30] is an open pit mine, that uses as processing methods CIP mill, heap leach and gravity. Production from heap leach began in late 2009. Ridgeway underground mine [23] produces gold and copper. It is in the process of transitioning from the sub-level cave to a block cave beneath the existing mine. Crushed ore from the underground is delivered by conveyor to a surface stockpile. Gold andcopper are then recovered in a conventional floatation circuit to produce a copper concentrate containing elevated gold levels. The next step is to pump to the filtration plant where it is dewatered prior to being exported to smelters throughout East Asia.

    Wharf [32] is an open pit and heap leach mine that has been in operation since 1983.

    Barneys Canyon gold mine [33] is an open pit mine that started production in 1989. Mining and milling ended in 2001. Gold production from stockpiles continued until 2005.

    Kettle River-Buckhorn gold mine [30], was originally conceived as an open pit mine, but it was redesigned and developed as an underground mine. The primary mining method employed is cut and fill. Its ore is processed through milling, flotation and CIP processes.

    Pogo gold mine [33] is an underground mine that utilizes a cut and fill drift method. The milling operation includes grinding, sulfide flotation, paste thickening, leach/CIP, cyanide detoxification, tailings filtration and gravity recovery.

    Open pit mining in USA is characterized by negative progress ratios, but underground mining using CIL and CIP shows positive progress ratios. Available data: from 2002 through 2007.

    3 Summary of the results

    Assuming that all mines of the same kind of operation as well as recovery process for a specific country are comparable, progress ratios can be presented as figure 2 displays.

    For instance, Australia has an excellent progress ratio when CIP technology is used either in open pit or underground mines. This can imply that gold mining industry in Australia has overcome the declining in ore grades through technological learning. A compilation of the best practices and all mining process in general would be very useful for mines using the same recovery process around the world. The sharing of operational and technical experiences, with countries such as Papua New Guinea would be an excellent way to improve the efficiency in the gold mining sector.

    For the United States, positive progress ratios can be observed when underground mining is performed (either when CIP or CIL process are applied). Hence, the relevant fact here is the kind of mining operation used: underground. Performance benchmarking of gold mines in Canada can be a worthwhile action to improve practices in the gold mining industry.

    In South America, countries like Argentina and Brazil show great positive progress ratio when operations in open pit mines with heap in leach technology as recovery process is employed. Again, it would be very useful an extended compilation of their best practices in order to share this information with countries that have mines with the same geological and technological characteristics, such as those in Peru.

    4 Conclusions

    This paper has studied the influence of technical development and declining ore grades on the availability of world gold resources, applying the learning curves approach and estimating progress ratios for each country. The latter allowed us to identify mines in which mining operations have proved to be successful when the goal is to save energy. Therefore these estimates can be used to point out best mining practices and serve as a reference for other mines with similar conditions.

    Fig. 2 Progress ratio for different recovery process and countries in gold mining industry.

    Average progress ratios obtained between different operation and recovery processes ranged from + 20% to – 22%. The learning effect is measured in terms of reduction in the energy requirements of mining operations.

    It should be pointed out, that the improvement in mining technologies, represented in this paper by the progress ratios calculated for different countries, mines operations and recovery processes are not related to time or cumulative production as it happens to conventional applications (such as manufacturing) when the theory of learning curves is applied. In the mining sector, an additional factor needs to be taken into account, and that is the key variable ore grade change. This way, an improvement in the energy efficiency of the processes does not necessarily imply an overall energy reduction, since the decrease in the ore grade may dominate.

    General results suggest that although progress in technology has been made, in most cases energy requirements are increasing, because the main variable is the ore grade. Therefore, it can be asserted that technology cannot in general avert the rising energy demand for gold mining in the future if no major changes are performed in gold mines around the world.

    It is crucial to analyze carefully those countries that are and will be the major gold producers such as Australia, South Africa, Russia, Chile, United States and Indonesia. The data analyzed reveals that South Africa and Australia show the greatest energy consumptions and hence should increase their efforts in improving their mining practices. Additionally, due to the strategic position of China in the gold mining industry, analyzing its data sets in energy consumptions and ore grades would be also very interesting and profitable.

    This survey has been carried out for gold, but future studies will be accomplished to other important commodities. This will allow us to have a broader understanding of the mining sector and the outcomes of technology evolution together with ore grade declining.

    Acknowledgements

    This paper has been financed by the IDERE II project from the Spanish Ministry of Industry and Science. We thank Dr. Gavin Mudd for sharing with us his comprehensive and useful data set of global gold mining.

    Nomenclature

    bConstant reflecting the rate energy decrease from year to year (learning index)

    cElasticity of learning by researching

    KSKnowledge stock

    RGas constant (8.3145 J/molK)

    SEnergy slope expressed as a decimal value (learning rate)

    T0Reference Temperature (298.15 K)

    xSequential number of the unit for which the energy is to be computed

    XcOre grade

    xiMolar concentration of substance i

    Y0Theoretical energy of the first production unit

    YxEnergy required to produce the xth unit

    Abbreviations

    CIP Circuit in Pulp

    CIL Circuit in Leach

    HL Heap Leach

    MIX Mixed (open pit and underground)

    OP Open Pit

    PR Progress ratio

    UG Underground

    UGt Underground tailings

    [1] Placer Dome Asia Pacific (1998),Porgera Mine Sustainable Report, PDAP, Milton.

    [2] Mudd, G. (2007), Global Trends in Gold Mining: Towards Quantifying Environmental and Resource Sustainability?,Resources Policy, 32, 42-56.

    [3] Mudd, G. (2007), Gold Mining in Australia: Linking Historical Trends and Environmental and Resource Sustainability,Environmental science & policy, 10, 629-644.

    [4] U.S. Geological Survey. USGS (2011), Mineral Commodities Summaries, U.S. Department of the Interior. Available at: <http://minerals.usgs.gov/minerals/pubs/mcs/2011/mcs2011.pdf > [accessed 18.1.2012].

    [5] Ruth, M. (1993),Integrating Economics, Ecology and Thermodynamics, Kluwer Academic Publishers: The Netherlands.

    [6] Soderholm, P. and Sundqvist, T. (2007), Empirical challenges in the use of learning curves for assessing the economic prospects of renewable energy technologies,Renewable Energy, 32, 2559-2578.

    [7] Giurco, D., Prior, T., Mudd, G., Mason, L. and Behrisch J. (2010),Peak Minerals in Australia: A Review of Changing Impacts and Benefits, Technical Report, Institute for Sustainable Futures, University of Technology, Sydney and Department of Civil Engineering, Monash University, Australia.

    [8] U.S. Geological Survey. USGS. (2011),Minerals Yearbook Gold, Technical Report.

    [9] Yelle, L. (1979),The Learning Curve: Historical Review and Comprehensive Survey, University of Lowell, 10, 302-328.

    [10] Ruth, M. (1995), Thermodynamic constraints on optimal depletion of copper and aluminum in the United States: A dynamic model of substitution and technical change,Ecological Economics, 15, 197-213.

    [11] Kahouli-Brahmi, S. (2008), Technological learning in energy environmental economy modelling: A survey,Energy Policy, 36, 138-162.

    [12] Weiss, M., Junginger, M., Patel, M. and Blok, K. (2010), A review of experience curve analyses for energy demand technologies,Technological Forecasting & Social Change, 77, 411-428.

    [13] Jamasb, T. and Kohler, J. (2007),Learning Curves for Energy Technology and Policy Analysis: A Critical Assessment, University of Cambridge, UK.

    [14] McDonald, A. and Schrattenholzer, L. (2001), Learning rates for energy technologies, Energy Policy, 29, 255-261.

    [15] De Andrade, L. (2007), Dynamic simulation of the carbon-in-pulp and carbon-in-leach processes,Brazilian Journal of Chemical Engineering, 24(04), 623-635.

    [16] Barrick Company. (2012), Available at: < http://www.barrick.com/GlobalOperations > [accessed 18.1.2012].

    [17] Valero, Al., Valero, A. and Domínguez, A. (2011), Influence of technical development and declining ore grades on the availability of gold resources, SDEWES 2011, In:Proceedings of the 6th Dubrovnik Conference on Sustainable Development of Energy, Water and Environment Systems, Sept 25-29, Dubrovnik, Croatia.

    [18] Mulligan, D. (1996),Environmental Management in the Australian Minerals and Energy Industries. Principles and Practices, Australia,Australia: University of New South Wales Press.

    [19] Unity Mining Limited (2012), Available at: < http://www.unitymining.com.au/ > [accessed 7.5.2012].

    [20] The Superpit (2012). Available at: < http://www.superpit.com.au/Production/MineralProcessing > [accessed 7.5.2012].

    [21] Gold Fields (2011), Agnew Gold Mine Technical Short Form Report, Available at:< http://www.goldfields.co.za/pdfs/technical_short_forms_2011/agnew_mine.pdf > [accessed 7.5.2012].

    [22] Gold Fields (2011), St Ives Gold Mine Technical Short Form Report, Available at:< http://www.goldfields.co.za/pdfs/technical_short_forms_2011/st_ives_mine.pdf > [accessed 7.5.2012].

    [23] Mining Technology (2012), Available at: < http://www.mining-technology.com/projects/ > [accessed 18.1.2012].

    [24] Normandy Mining Limited (1998), Environment Report, Mt Leyshon Operations, Available at:< http://www.corporateregister.com/a10723/nml-ml98-se-az.pdf > [accessed 18.1.2012].

    [25] Normandy Mining Limited (1998) Environment Report, Tanami Operations, Available at:< http://www.corporateregister.com/a10723/nml-tan98-se-az.pdf > [accessed 18.1.2012].

    [26] Evolution Mining (2012), Available at: < http://www.evolutionmining.com.au/ > [accessed 18.1.2012].

    [27] AngloGold Ashanti (2012), Available at: < http://www.anglogold.co.za/Home > [accessed 18.1.2012].

    [28] Minesite (2012), Available at: < http://minesite.com/ > [accessed 18.1.2012].

    [29] Lloyd, P., Berthelsen, R. and Strom, E. (2009), Australia: New South Wales, Technical Report on Peak Gold Mines.

    [30] Kinross (2012), Available at: < http://www.kinross.com/ > [accessed 18.1.2012].

    [31] Newgold (2012), Available at: < http://newgold.com/ > [accessed 18.1.2012].

    [32] Goldcorp (2012), Available at: < http://www.goldcorp.com > [accessed 18.1.2012].

    [33] Global Infomine (2012), Available at: < http://www.infomine.com/minesite/ > [accessed 18.1.2012].

    [34] Gold Fields (2012), Available at: < http://www.goldfields.co.za/ > [accessed 18.1.2012].

    [35] McGuire, G. (2003),Managing Mine Closure Risks in Developing Communities - A Case Study, Kelian Equatorial Mining, Indonesia, Mining Risk Management Conference, Sept 9-12, Sydney, NSW.

    [36] Minmetals Resources Limited (2012), Available at: < http://www.mmg.com/pages/828.aspx > [accessed 18.1.2012].

    [37] IamGold Corporation (2012), Available at: < http://www.iamgold.com/English/Operations/default.aspx > [accessed 18.1.2012].

    [38] RandGold Resources (2012), Available at: < http://www.randgoldresources.com/randgold/content/en/2009/randgold-home> [accessed 18.1.2012].

    [39] Primero Mining (2012), Available at: < http://www.primeromining.com/Operations/San-Dimas-Mine/default.aspx > [accessed 18.1.2012].

    [40] AditNow (2012), Available at: < http://www.aditnow.co.uk/ > [accessed 18.1.2012].

    [41] Barrick Company (2012), Available at:< http://www.barrick.com/Theme/Barrick/files/docs_presentations/pr11_12_2003_weauau.pdf > [accessed 7.5.2012].

    [42] Ausenco (2012), Available at: < http://www.ausenco.com/page/Our_Projects/Pierina_Gold_Mine/ >[accessed 18.1.2012].

    [43] Harmony (2012), Available at: < http://www.harmony.co.za/ > [accessed 18.1.2012].

    [44] Gold mining in Tanzania (2012), Available at: < http://www.tanzaniagold.com/ > [accessed 18.1.2012].

    26 January 2013

    ?Corresponding author.

    Email address: adrianad@unizar.es

    ISSN 2325-6192, eISSN 2325-6206/$- see front materials ? 2013 L&H Scientific Publishing, LLC. All rights reserved.

    10.5890/JEAM.2013.01.007

    Accepted 25 February 2013

    Available online 2 April 2013

    国产精品一区二区在线不卡| 国产乱来视频区| 在线观看美女被高潮喷水网站| 久久ye,这里只有精品| 啦啦啦在线观看免费高清www| av播播在线观看一区| 中文字幕av成人在线电影| 亚洲性久久影院| 精品亚洲成国产av| 欧美高清性xxxxhd video| 人妻系列 视频| 日本一二三区视频观看| 日韩av免费高清视频| 26uuu在线亚洲综合色| 国产高潮美女av| 亚洲,欧美,日韩| 免费黄频网站在线观看国产| 六月丁香七月| 草草在线视频免费看| 永久免费av网站大全| 色5月婷婷丁香| 伊人久久国产一区二区| 下体分泌物呈黄色| 99九九线精品视频在线观看视频| 免费不卡的大黄色大毛片视频在线观看| 亚洲熟女精品中文字幕| 国产高潮美女av| 国产在线男女| 九九爱精品视频在线观看| 亚洲欧美一区二区三区国产| 欧美xxxx黑人xx丫x性爽| 成人影院久久| 欧美bdsm另类| 亚洲真实伦在线观看| av.在线天堂| 亚洲经典国产精华液单| 成年女人在线观看亚洲视频| 欧美精品亚洲一区二区| 丰满乱子伦码专区| 亚洲精品色激情综合| 九九久久精品国产亚洲av麻豆| 国产 一区精品| 午夜福利在线在线| 熟女电影av网| 国产精品99久久久久久久久| 免费看不卡的av| 色5月婷婷丁香| 国产精品一区二区性色av| 亚洲熟女精品中文字幕| 欧美国产精品一级二级三级 | 久久久久久久久大av| 亚洲国产欧美人成| 国产片特级美女逼逼视频| 一级av片app| 小蜜桃在线观看免费完整版高清| 熟女电影av网| 一区在线观看完整版| 国产男人的电影天堂91| 精品人妻偷拍中文字幕| 国产午夜精品久久久久久一区二区三区| 久久久久精品久久久久真实原创| 一区二区av电影网| 91久久精品国产一区二区成人| 亚洲av电影在线观看一区二区三区| 男女下面进入的视频免费午夜| 久久久久久伊人网av| 日本色播在线视频| 亚洲国产欧美在线一区| 亚洲国产最新在线播放| 日韩欧美精品免费久久| 国产精品一二三区在线看| 国产精品麻豆人妻色哟哟久久| 国产毛片在线视频| 两个人的视频大全免费| www.色视频.com| 欧美少妇被猛烈插入视频| 综合色丁香网| 狂野欧美激情性xxxx在线观看| 日本vs欧美在线观看视频 | 国产午夜精品久久久久久一区二区三区| 日韩一区二区视频免费看| av线在线观看网站| 欧美xxxx性猛交bbbb| 亚洲精品日本国产第一区| 美女cb高潮喷水在线观看| 人妻少妇偷人精品九色| 欧美xxxx性猛交bbbb| 国产黄色视频一区二区在线观看| 最近中文字幕高清免费大全6| 男女国产视频网站| 日韩强制内射视频| 我要看日韩黄色一级片| 亚洲av福利一区| 99久久中文字幕三级久久日本| 亚洲av国产av综合av卡| 国产日韩欧美亚洲二区| 一级片'在线观看视频| 色网站视频免费| 亚洲国产精品999| 麻豆成人av视频| 91精品国产九色| 天堂俺去俺来也www色官网| 啦啦啦中文免费视频观看日本| av在线蜜桃| 人人妻人人澡人人爽人人夜夜| 午夜免费观看性视频| 日本欧美国产在线视频| 日韩中文字幕视频在线看片 | 国产成人免费无遮挡视频| 自拍欧美九色日韩亚洲蝌蚪91 | 久久av网站| 欧美成人午夜免费资源| av在线老鸭窝| 观看免费一级毛片| 亚洲精品一区蜜桃| 国产免费又黄又爽又色| 乱码一卡2卡4卡精品| 少妇人妻精品综合一区二区| 欧美3d第一页| 最近2019中文字幕mv第一页| 国产亚洲最大av| 一级毛片 在线播放| 草草在线视频免费看| 亚洲电影在线观看av| 日本黄色片子视频| 国产淫片久久久久久久久| 一级黄片播放器| 亚洲,一卡二卡三卡| 丰满迷人的少妇在线观看| 精品少妇久久久久久888优播| 一级二级三级毛片免费看| 国产国拍精品亚洲av在线观看| 欧美日韩综合久久久久久| 黄色日韩在线| 国产熟女欧美一区二区| 国产成人免费观看mmmm| 久久精品久久精品一区二区三区| a级毛色黄片| 国产伦精品一区二区三区四那| 午夜福利在线观看免费完整高清在| 欧美亚洲 丝袜 人妻 在线| 日本与韩国留学比较| 美女国产视频在线观看| 免费大片18禁| 免费看av在线观看网站| 欧美变态另类bdsm刘玥| 国产高潮美女av| 国产男人的电影天堂91| 熟女人妻精品中文字幕| 国产在线一区二区三区精| 日韩一区二区视频免费看| 久久久精品免费免费高清| 亚洲精品第二区| 国产精品一区www在线观看| 免费观看无遮挡的男女| av在线播放精品| 视频中文字幕在线观看| 国产av国产精品国产| 午夜免费鲁丝| 少妇猛男粗大的猛烈进出视频| 国产免费视频播放在线视频| 日本一二三区视频观看| av国产久精品久网站免费入址| 久久97久久精品| 毛片一级片免费看久久久久| av国产精品久久久久影院| 卡戴珊不雅视频在线播放| 男男h啪啪无遮挡| 一本久久精品| 欧美xxxx黑人xx丫x性爽| 国产精品久久久久成人av| 中文字幕精品免费在线观看视频 | 国产精品一区二区在线不卡| 欧美一区二区亚洲| 91精品国产国语对白视频| 观看美女的网站| 一本色道久久久久久精品综合| 久久久久久伊人网av| 国产一区亚洲一区在线观看| 各种免费的搞黄视频| 一级a做视频免费观看| 在线观看免费高清a一片| 99热这里只有是精品在线观看| 精品亚洲乱码少妇综合久久| av专区在线播放| 亚洲精华国产精华液的使用体验| av福利片在线观看| 国产亚洲5aaaaa淫片| 亚洲天堂av无毛| 国产精品成人在线| 91午夜精品亚洲一区二区三区| 日本-黄色视频高清免费观看| 亚洲精品乱码久久久v下载方式| 精品人妻一区二区三区麻豆| 一个人免费看片子| 国产 一区 欧美 日韩| av在线app专区| 老师上课跳d突然被开到最大视频| 99热这里只有精品一区| 精品亚洲成国产av| 舔av片在线| 九九久久精品国产亚洲av麻豆| 国产精品秋霞免费鲁丝片| 精品国产三级普通话版| 汤姆久久久久久久影院中文字幕| 男女免费视频国产| 在线看a的网站| 身体一侧抽搐| 欧美日韩一区二区视频在线观看视频在线| 国产在线免费精品| 18禁动态无遮挡网站| 亚洲欧美日韩另类电影网站 | 日韩,欧美,国产一区二区三区| a级一级毛片免费在线观看| 国产精品人妻久久久久久| 国产一区有黄有色的免费视频| 男人和女人高潮做爰伦理| 欧美日韩国产mv在线观看视频 | 建设人人有责人人尽责人人享有的 | 噜噜噜噜噜久久久久久91| 有码 亚洲区| 精品久久久久久电影网| 欧美区成人在线视频| 国产成人freesex在线| 青青草视频在线视频观看| 国产免费福利视频在线观看| 亚洲经典国产精华液单| 国产精品蜜桃在线观看| 91久久精品国产一区二区成人| 少妇裸体淫交视频免费看高清| 国产精品久久久久久av不卡| 久久99热这里只频精品6学生| 日韩大片免费观看网站| 国产精品一及| 99热网站在线观看| 我的女老师完整版在线观看| 色婷婷av一区二区三区视频| 精品国产三级普通话版| 久久久久久九九精品二区国产| 九草在线视频观看| 久久av网站| av国产久精品久网站免费入址| 亚洲欧洲日产国产| 视频中文字幕在线观看| 观看美女的网站| 成人无遮挡网站| 最近2019中文字幕mv第一页| 成年免费大片在线观看| 在线免费十八禁| 99热全是精品| 99久久中文字幕三级久久日本| 国产成人精品婷婷| 少妇裸体淫交视频免费看高清| 国产精品欧美亚洲77777| 高清日韩中文字幕在线| 亚州av有码| 欧美日韩在线观看h| 丰满人妻一区二区三区视频av| 欧美国产精品一级二级三级 | 国产久久久一区二区三区| 丝袜喷水一区| 久久久a久久爽久久v久久| 久久久久久人妻| 免费黄频网站在线观看国产| 国产老妇伦熟女老妇高清| 午夜福利视频精品| 久热久热在线精品观看| 欧美高清成人免费视频www| 我的老师免费观看完整版| 久久精品国产自在天天线| 国产精品人妻久久久影院| 午夜免费鲁丝| 国产精品嫩草影院av在线观看| 欧美成人a在线观看| 天美传媒精品一区二区| 欧美一区二区亚洲| 一二三四中文在线观看免费高清| 一区二区三区免费毛片| 国产精品.久久久| 女人久久www免费人成看片| 亚洲av成人精品一区久久| 欧美人与善性xxx| 亚洲最大成人中文| 老司机影院毛片| 两个人的视频大全免费| 亚洲av国产av综合av卡| 精品人妻视频免费看| 哪个播放器可以免费观看大片| 婷婷色综合大香蕉| 日本黄大片高清| 日韩一本色道免费dvd| 日本欧美视频一区| 一级毛片aaaaaa免费看小| 韩国高清视频一区二区三区| 免费看av在线观看网站| 秋霞在线观看毛片| 国产亚洲91精品色在线| 一级毛片 在线播放| www.色视频.com| 十分钟在线观看高清视频www | 久久韩国三级中文字幕| 日本av手机在线免费观看| 国产免费视频播放在线视频| 亚洲aⅴ乱码一区二区在线播放| 精品久久久精品久久久| 日韩免费高清中文字幕av| 色婷婷久久久亚洲欧美| 欧美xxxx性猛交bbbb| 日韩不卡一区二区三区视频在线| 黄片wwwwww| 观看av在线不卡| 欧美xxⅹ黑人| 亚洲精品成人av观看孕妇| 丝袜脚勾引网站| 熟女人妻精品中文字幕| 国产精品人妻久久久影院| av一本久久久久| 成人18禁高潮啪啪吃奶动态图 | 黄色日韩在线| 国产免费福利视频在线观看| 国产成人a区在线观看| 赤兔流量卡办理| 国产精品一区二区三区四区免费观看| 亚洲av欧美aⅴ国产| 亚洲欧美日韩无卡精品| 91久久精品电影网| 黄色配什么色好看| 大话2 男鬼变身卡| 只有这里有精品99| 一级片'在线观看视频| 麻豆成人午夜福利视频| 国产女主播在线喷水免费视频网站| 亚洲欧美成人综合另类久久久| 欧美精品人与动牲交sv欧美| 亚洲伊人久久精品综合| 观看美女的网站| 午夜福利视频精品| 丝袜脚勾引网站| 久久久久久人妻| 欧美成人一区二区免费高清观看| 王馨瑶露胸无遮挡在线观看| 一级黄片播放器| 久久这里有精品视频免费| 久久亚洲国产成人精品v| 婷婷色麻豆天堂久久| 最黄视频免费看| 国产精品无大码| 有码 亚洲区| 国产美女午夜福利| 国产高清三级在线| 三级经典国产精品| av在线观看视频网站免费| 高清黄色对白视频在线免费看 | 免费av中文字幕在线| 亚洲精品中文字幕在线视频 | 肉色欧美久久久久久久蜜桃| 精品人妻视频免费看| 超碰av人人做人人爽久久| 韩国高清视频一区二区三区| 一级爰片在线观看| 亚洲成人av在线免费| 亚洲精品久久久久久婷婷小说| 久久久国产一区二区| 97热精品久久久久久| 内地一区二区视频在线| 岛国毛片在线播放| 国产av精品麻豆| 3wmmmm亚洲av在线观看| 黄片wwwwww| 中国国产av一级| 国产老妇伦熟女老妇高清| 中文字幕人妻熟人妻熟丝袜美| tube8黄色片| 亚洲人成网站在线观看播放| 精品国产露脸久久av麻豆| 成人黄色视频免费在线看| 日韩一本色道免费dvd| 十分钟在线观看高清视频www | 亚洲国产精品专区欧美| 2021少妇久久久久久久久久久| 国产色爽女视频免费观看| 亚洲成人av在线免费| 久久久久国产网址| 国产精品无大码| 舔av片在线| 天堂俺去俺来也www色官网| 国产欧美日韩一区二区三区在线 | 国产免费一级a男人的天堂| 伦理电影免费视频| 最后的刺客免费高清国语| 直男gayav资源| 不卡视频在线观看欧美| 午夜福利在线在线| 国产成人精品婷婷| 人人妻人人添人人爽欧美一区卜 | 涩涩av久久男人的天堂| 亚洲中文av在线| 日产精品乱码卡一卡2卡三| 成人免费观看视频高清| 免费人妻精品一区二区三区视频| 中国三级夫妇交换| 在线观看美女被高潮喷水网站| 久久久久网色| 午夜激情福利司机影院| 水蜜桃什么品种好| 成年免费大片在线观看| 中文字幕久久专区| 尤物成人国产欧美一区二区三区| 日韩成人伦理影院| 天堂中文最新版在线下载| 在线观看三级黄色| 在线免费十八禁| 另类亚洲欧美激情| av视频免费观看在线观看| 日本黄大片高清| 少妇人妻一区二区三区视频| 精品国产乱码久久久久久小说| 精品久久久久久久久亚洲| 丰满人妻一区二区三区视频av| 深爱激情五月婷婷| 美女视频免费永久观看网站| 最近最新中文字幕大全电影3| 久久久精品免费免费高清| 亚洲第一区二区三区不卡| 波野结衣二区三区在线| 欧美三级亚洲精品| 男女边吃奶边做爰视频| 午夜福利影视在线免费观看| 中文字幕亚洲精品专区| h日本视频在线播放| www.av在线官网国产| 欧美日本视频| 亚洲最大成人中文| 精品视频人人做人人爽| 亚洲精华国产精华液的使用体验| 亚洲成色77777| 欧美日韩在线观看h| 视频中文字幕在线观看| 女人十人毛片免费观看3o分钟| 亚洲精品国产色婷婷电影| 亚洲国产欧美人成| 欧美一区二区亚洲| 久久6这里有精品| 天天躁日日操中文字幕| 2021少妇久久久久久久久久久| 久久久色成人| 乱系列少妇在线播放| 少妇熟女欧美另类| 干丝袜人妻中文字幕| 日韩 亚洲 欧美在线| 亚洲成人一二三区av| 日本爱情动作片www.在线观看| 久久综合国产亚洲精品| 91在线精品国自产拍蜜月| 久久97久久精品| 婷婷色综合www| 丝袜喷水一区| 1000部很黄的大片| 一本—道久久a久久精品蜜桃钙片| 中国国产av一级| 国产老妇伦熟女老妇高清| 国产精品蜜桃在线观看| 日日摸夜夜添夜夜添av毛片| 亚洲第一区二区三区不卡| 国产精品无大码| 久久影院123| 久久人人爽人人片av| a级一级毛片免费在线观看| 亚洲av日韩在线播放| 18禁裸乳无遮挡动漫免费视频| 亚洲婷婷狠狠爱综合网| 特大巨黑吊av在线直播| 在线精品无人区一区二区三 | 99热网站在线观看| 在线观看免费高清a一片| 晚上一个人看的免费电影| 人妻一区二区av| 日本与韩国留学比较| 国产精品一区二区在线不卡| 日本黄色片子视频| 插逼视频在线观看| 综合色丁香网| 亚洲第一av免费看| 精品国产三级普通话版| 亚洲欧美日韩另类电影网站 | 欧美xxⅹ黑人| 美女xxoo啪啪120秒动态图| 又爽又黄a免费视频| 男女啪啪激烈高潮av片| 啦啦啦中文免费视频观看日本| 欧美97在线视频| 免费人妻精品一区二区三区视频| 日韩中字成人| 菩萨蛮人人尽说江南好唐韦庄| 十分钟在线观看高清视频www | 日本wwww免费看| 国产精品国产三级国产av玫瑰| 成人18禁高潮啪啪吃奶动态图 | 亚洲国产色片| 日韩一区二区三区影片| 狂野欧美白嫩少妇大欣赏| 内地一区二区视频在线| 尤物成人国产欧美一区二区三区| 精品视频人人做人人爽| 老师上课跳d突然被开到最大视频| 日韩在线高清观看一区二区三区| 人人妻人人澡人人爽人人夜夜| 亚洲激情五月婷婷啪啪| 亚洲av.av天堂| 黄色怎么调成土黄色| 久久精品夜色国产| 干丝袜人妻中文字幕| 日韩成人av中文字幕在线观看| 久久久久网色| 熟妇人妻不卡中文字幕| 成人午夜精彩视频在线观看| 国产有黄有色有爽视频| 永久免费av网站大全| 亚洲欧美成人综合另类久久久| 麻豆国产97在线/欧美| 午夜福利视频精品| 99热这里只有是精品在线观看| 久久精品国产a三级三级三级| 美女中出高潮动态图| 国产精品一区二区三区四区免费观看| 亚洲欧美精品自产自拍| 亚洲成人中文字幕在线播放| 搡老乐熟女国产| 女性被躁到高潮视频| 久久久久久人妻| 欧美人与善性xxx| 亚洲第一区二区三区不卡| 国产 一区精品| 国产成人精品婷婷| 婷婷色av中文字幕| 国产在线视频一区二区| 99热国产这里只有精品6| 久久青草综合色| 国产精品蜜桃在线观看| 一个人看的www免费观看视频| 3wmmmm亚洲av在线观看| 国产精品女同一区二区软件| 国产中年淑女户外野战色| 丝瓜视频免费看黄片| 高清视频免费观看一区二区| 亚洲av欧美aⅴ国产| 国产精品一区二区在线不卡| 午夜日本视频在线| 午夜福利在线在线| 久久人人爽人人爽人人片va| 成人漫画全彩无遮挡| 国产 精品1| 午夜福利影视在线免费观看| 欧美成人午夜免费资源| 伦精品一区二区三区| 国产在线男女| 欧美+日韩+精品| 国产欧美亚洲国产| 久久国产乱子免费精品| 久久人人爽人人爽人人片va| 一级黄片播放器| 亚洲av中文字字幕乱码综合| 制服丝袜香蕉在线| 日韩制服骚丝袜av| 美女内射精品一级片tv| 极品教师在线视频| 日日摸夜夜添夜夜添av毛片| 欧美激情国产日韩精品一区| 成人毛片a级毛片在线播放| 精品久久久久久久久亚洲| 夜夜骑夜夜射夜夜干| 九草在线视频观看| 夫妻午夜视频| 啦啦啦中文免费视频观看日本| 国产精品蜜桃在线观看| www.av在线官网国产| 在线观看一区二区三区| 亚洲aⅴ乱码一区二区在线播放| 国产69精品久久久久777片| 亚洲国产日韩一区二区| 黄片wwwwww| 欧美日韩视频精品一区| 欧美zozozo另类| 老熟女久久久| 精品亚洲成a人片在线观看 | 免费不卡的大黄色大毛片视频在线观看| 久久99热这里只频精品6学生| 建设人人有责人人尽责人人享有的 | 看免费成人av毛片| 婷婷色麻豆天堂久久| 久久人人爽av亚洲精品天堂 | 黑人高潮一二区| 久久综合国产亚洲精品| 国产深夜福利视频在线观看| 日本免费在线观看一区| 久久影院123| 精品视频人人做人人爽| 街头女战士在线观看网站| 国产成人a∨麻豆精品| 成人美女网站在线观看视频| 看非洲黑人一级黄片| 中文字幕精品免费在线观看视频 | 国产永久视频网站| 搡老乐熟女国产| 欧美一级a爱片免费观看看| av国产免费在线观看| 国产精品伦人一区二区| 边亲边吃奶的免费视频| 丰满少妇做爰视频| 欧美人与善性xxx| 欧美国产精品一级二级三级 | av又黄又爽大尺度在线免费看| 99久久人妻综合| 黑丝袜美女国产一区| 久久国产亚洲av麻豆专区|